Structural Chemistry

, 22:1225 | Cite as

Structural insight into repeated-rhomboid coordination polymers from 4,4′-dithiodipyridine and zinc nitrate

  • Rüdiger W. Seidel
  • Christina Dietz
  • Iris M. Oppel
Original Research

Abstract

Reaction of Zn(NO3)2·6H2O with the bent bridging ligand 4,4′-dithiodipyridine (dtdp), showing axial chirality, in the presence of the chelating 1,10-phenanthroline (phen) ligand in ethanol yielded [{Zn(μ-dtdp)2(H2O)2}(NO3)2·2C2H5OH·2H2O]n (1). In 1, Zn2+ ions are linked by two dtdp ligands of opposite chirality into a one-dimensional coordination polymer of the repeated-rhomboid type; the phen co-ligand was not encountered in the crystal. Pseudo-symmetry of the lattice is discussed for 1. Reaction of Zn(NO3)2·6H2O and dtdp in an ethanol/water mixture in absence of phen led to the known repeated-rhomboid coordination polymer [{Zn(NO3)(μ-dtdp)2(H2O)}NO3·4H2O]n (2), the crystal structure of which was redetermined at 110 K. At low temperature, the nitrato-κO ligand in one axial position of Zn2+ was found to be non-disordered as distinct from the room temperature structure (Horikoshi and Mikuriya, Cryst Growth Des 5:223–230, 2005). The Zn2+ ions in 2 are joined by two dtdp ligands of the same chirality.

Keywords

Coordination polymer 4,4′-Dithiodipyridine Zinc Crystal structure 

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Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  • Rüdiger W. Seidel
    • 1
  • Christina Dietz
    • 2
  • Iris M. Oppel
    • 3
  1. 1.Lehrstuhl für Analytische ChemieRuhr-Universität BochumBochumGermany
  2. 2.Lehrstuhl für Anorganische ChemieTechnische Universität DortmundDortmundGermany
  3. 3.Institut für Anorganische ChemieRheinisch-Westfälische Technische Hochschule AachenAachenGermany

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