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Structural Chemistry

, Volume 19, Issue 2, pp 285–290 | Cite as

Synthesis, spectral and thermal properties, and crystal structure of catena-poly-μ-ethylenediamine(dipicolinato)zinc(II) trihydrate, {[Zn(dipic)(μ-en)]·3H2O} n

  • Alper Tolga Çolak
  • Okan Zafer Yeşilel
  • Tuncer Hökelek
  • Ertan Şahin
Original Research

Abstract

A novel metal–organic coordination polymer framework formulated as {[Zn(dipic)(μ-en)]·3H2O} n (1) (catena-poly-μ-ethylenediamine(dipicolinato)zinc(II) trihydrate) has been synthesized and characterized by spectral method (IR), elemental analysis, thermal analysis (TG, DTG, DTA) and single crystal X-ray diffraction techniques. It crystallizes in the triclinic system, space group P−1. The asymmetric unit contains three hydrogen-bonded water molecules and the Zn atom is five-coordinated by three N and two O atoms. In fact, it is a new one-dimensional zinc complex with the peculiarity of having the ethylenediamine ligand very unusually acting as bridge to form polymeric chains. In the crystal structure, intramolecular O–H···O and intermolecular O–H···O and N–H···O hydrogen bonds result in the formation of a supramolecular structure, in which they seem to be effective in the stabilization of the structure.

Keywords

Dipicolinato complex Zinc(II) complex Bridged ethylenediamine 

Notes

Acknowledgments

The authors are indebted to the Dumlupinar University Research Found for support (grant No: 2007/14) and Department of Chemistry, Atatürk University, Erzurum, Turkey, for the use of X-ray diffractometer purchased under grant No. 2003/219 of the University Research Fund.

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Copyright information

© Springer Science+Business Media, LLC 2008

Authors and Affiliations

  • Alper Tolga Çolak
    • 1
  • Okan Zafer Yeşilel
    • 2
  • Tuncer Hökelek
    • 3
  • Ertan Şahin
    • 4
  1. 1.Department of Chemistry, Faculty of Arts and SciencesDumlupınar UniversityKutahyaTurkey
  2. 2.Department of Chemistry, Faculty of Arts and SciencesEskişehir Osmangazi UniversityEskisehirTurkey
  3. 3.Department of Physics Engineering, Faculty of EngineeringHacettepe UniversityAnkaraTurkey
  4. 4.Department of Chemistry, Faculty of Arts and SciencesAtatürk UniversityErzurumTurkey

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