Space Science Reviews

, Volume 137, Issue 1–4, pp 241–255 | Cite as

Tropospheric New Particle Formation and the Role of Ions

  • Jan Kazil
  • R. Giles Harrison
  • Edward R. Lovejoy
Open Access
Article

Abstract

Aerosol particles play an important role in the Earth’s troposphere and in the climate system: They scatter and absorb solar radiation, facilitate chemical processes, and serve as condensation nuclei for the formation of clouds. Tropospheric aerosol particles are emitted from surface sources or form in situ from the gas phase. Formation from the gas phase requires concentrations of aerosol precursor molecules aggregating to form molecular clusters able to grow faster than they evaporate. This process is called nucleation. Gas phase ions can reduce the concentration of aerosol precursor molecules required for nucleation, as they greatly stabilize molecular clusters with respect to evaporation. Therefore, ions are a potential source of aerosol particles. Since atmospheric ionization carries the signal of the decadal solar cycle due to the modulation of the galactic cosmic ray intensity by solar activity, a possible connection between the solar cycle, galactic cosmic rays, aerosols, and clouds has been a long-standing focus of interest. In this paper, we provide an overview of theoretical, modeling, laboratory, and field work on the role and relevance of ions for the formation of tropospheric aerosol particles, and on subsequent effects on clouds, and discuss briefly related research needs.

Keywords

Troposphere Aerosol nucleation Ionization Cosmic rays Clouds 

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Copyright information

© Springer Science+Business Media B.V. 2008

Authors and Affiliations

  • Jan Kazil
    • 1
  • R. Giles Harrison
    • 2
  • Edward R. Lovejoy
    • 3
  1. 1.Max Planck Institute for MeteorologyHamburgGermany
  2. 2.Department of MeteorologyUniversity of ReadingReadingUK
  3. 3.NOAA Earth System Research LaboratoryChemical Sciences DivisionBoulderUSA

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