Synthesis and characterization of functionalized ferrocenylsilanes bearing a bulky substituent

Silicon Chemistry volume 3, pages199–207(2007)Cite this article

Abstract

Several types of overcrowded ferrocenylsilanes, Tbt(Fc)SiX2(Tbt=2, 4, 6-tris[bis(trimethylsilyl)methyl]phenyl, Fc=ferrocenyl, X = H, OH, and Br) were synthesized and characterized. In addition, DFT calculations for ferrocenylsilanediol systems indicated the existence of the intramolecular hydrogen bonding between the Fe atom and H–O moiety in Tbt(Fc)Si(OH)2.

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Affiliations

  1. Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto, 611-0011, Japan

    Takahiro Sasamori, Megumi Kobayashi, Noriyoshi Nagahora, Yusuke Sugiyama & Norihiro Tokitoh

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  1. Takahiro Sasamori
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  2. Megumi Kobayashi
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  3. Noriyoshi Nagahora
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  4. Yusuke Sugiyama
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  5. Norihiro Tokitoh
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Correspondence to Norihiro Tokitoh.

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Dedicated to Professor Mitsuo Kira on the occasion of his 2005 Wacker Awardy

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Sasamori, T., Kobayashi, M., Nagahora, N. et al. Synthesis and characterization of functionalized ferrocenylsilanes bearing a bulky substituent. Silicon Chem 3, 199–207 (2007). https://doi.org/10.1007/s11201-006-9010-y

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Key words

  • silicon
  • steric protection
  • ferrocene
  • cyclic voltammetry
  • hydrogen bond