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Russian Journal of Organic Chemistry

, Volume 41, Issue 6, pp 843–854 | Cite as

Synthesis and Structure of Bis-crown-Containing Stilbenes

  • A. I. Vedernikov
  • S. S. Basok
  • S. P. Gromov
  • L. G. Kuz’mina
  • V. G. Avakyan
  • N. A. Lobova
  • E. Yu. Kulygina
  • T. V. Titkov
  • Yu. A. Strelenko
  • E. I. Ivanov
  • J. A. K. Howard
  • M. V. Alfimov
Article

Abstract

An improved procedure was proposed for the synthesis of stilbenes fused to two crown ether fragments at both benzene rings. The structure of new homologous symmetric bis-crown-containing stilbenes was determined by X-ray analysis. Relations were revealed between the size of the crown ether moiety and stilbene conformation in crystal and the mode of crystal packing. Conformational analysis of the prepared stilbenes in solution and in the solid state was performed by 1H and 13C NMR spectroscopy and by DFT quantum-chemical calculations.

Keywords

Benzene Organic Chemistry Solid State Benzene Ring Crown Ether 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© MAIK “Nauka/Interperiodica” 2005

Authors and Affiliations

  • A. I. Vedernikov
    • 1
  • S. S. Basok
    • 2
  • S. P. Gromov
    • 1
  • L. G. Kuz’mina
    • 3
  • V. G. Avakyan
    • 1
  • N. A. Lobova
    • 1
  • E. Yu. Kulygina
    • 2
  • T. V. Titkov
    • 1
  • Yu. A. Strelenko
    • 4
  • E. I. Ivanov
    • 2
  • J. A. K. Howard
    • 5
  • M. V. Alfimov
    • 1
  1. 1.Photochemistry CenterRussian Academy of SciencesMoscowRussia
  2. 2.Bogatskii Physicochemical InstituteNational Academy of Sciences of UkraineOdessaUkraine
  3. 3.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia
  4. 4.Zelinskii Institute of Organic ChemistryRussian Academy of SciencesMoscowRussia
  5. 5.Chemistry DepartmentDurham UniversitySouth Road, DurhamUK

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