Russian Journal of General Chemistry

, Volume 75, Issue 9, pp 1367–1372 | Cite as

Reactions of Elemental Phosphorus with Electrophiles in Super Basic Systems: XVII. Phosphorylation of Arylalkenes with Active Modifications of Elemental Phosphorus

  • B. A. Trofimov
  • N. K. Gusarova
  • S. F. Malysheva
  • V. A. Kuimov
  • B. G. Sukhov
  • S. I. Shaikhudinova
  • N. P. Tarasova
  • Yu. V. Smetannikov
  • O. G. Sinyashin
  • Yu. G. Budnikova
  • T. I. Kazantseva
  • V. I. Smirnov
Article
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Abstract

The example of the phosphorylation of styrene and 2-vinylnaphthalene with elemental phosphorus in the KOH-DMSO system at room or elevated temperature was used to show that the activated red phosphorus prepared from white phosphorus under ionizing radiation has a reactivity comparable with that of white phosphorus and significantly higher than that of ordinary technical red phosphorus.

Keywords

Radiation Phosphorus Elevated Temperature Styrene Active Modification 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© MAIK "Nauka/Interperiodica" 2005

Authors and Affiliations

  • B. A. Trofimov
    • 1
  • N. K. Gusarova
    • 1
  • S. F. Malysheva
    • 1
  • V. A. Kuimov
    • 1
  • B. G. Sukhov
    • 1
  • S. I. Shaikhudinova
    • 1
  • N. P. Tarasova
    • 2
  • Yu. V. Smetannikov
    • 2
  • O. G. Sinyashin
    • 3
  • Yu. G. Budnikova
    • 3
  • T. I. Kazantseva
    • 1
  • V. I. Smirnov
    • 1
  1. 1.Favorskii Irkutsk Institute of Chemistry, Siberian BranchRussian Academy of SciencesIrkutskRussia
  2. 2.Mendeleev Russian University of Chemical TechnologyMoscowRussia
  3. 3.Arbuzov Institute of Organic and Physical Chemistry, Kazan Research CenterRussian Academy of SciencesKazan, TatarstanRussia

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