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Russian Journal of General Chemistry

, Volume 74, Issue 10, pp 1508–1512 | Cite as

Liquid-phase oxidation of tert-butyldimethylsilane

  • D. S. Lutsik-Maksim
  • V. I. Timokhin
  • A. B. Zaborovskii
  • R. E. Pristanskii
  • A. A. Turovskii
  • C. Chatgilialoglu
Article

Abstract

Kinetics and mechanism of liquid-phase oxidation of tert-butyldimethylsilane t-BuMe2SiH with molecular oxygen in the temperature range 297–350K were studied. Reaction orders in silane, initiator, and oxygen were evaluated. The major product of the oxidation of t-BuMe2SiH is tert-butyldimethylsilyl hydroperoxide t-BuMe2SiOOH. It was shown for the first time that the major reaction product is a silyl hydroperoxide. A kinetic scheme of the oxidation of t-BuMe2SiH is offered and discussed.

Keywords

Oxidation Oxygen Silane Hydroperoxide Molecular Oxygen 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© MAIK “Nauka/Interperiodica” 2004

Authors and Affiliations

  • D. S. Lutsik-Maksim
    • 1
    • 2
  • V. I. Timokhin
    • 1
    • 2
  • A. B. Zaborovskii
    • 1
    • 2
  • R. E. Pristanskii
    • 1
    • 2
  • A. A. Turovskii
    • 1
    • 2
  • C. Chatgilialoglu
    • 1
    • 2
  1. 1.Department of Physical Chemistry and Technology of Fossil Fuels, Pisarzhevskii Institute of Physical ChemistryNational Academy of Scienses of UkraineUkraine
  2. 2.Institute of Organic Synthesis and PhotoreactionsNational Scientific Council of ItalyBolognaItaly

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