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Russian Chemical Bulletin

, Volume 68, Issue 8, pp 1570–1574 | Cite as

Solid-phase synthesis of boron carbides ReB2C (Re = Ho, Tm, Lu) of rare earth elements

  • S. V. Kuznetsov
  • E. Y. AfonyushkinaEmail author
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Abstract

Approaches to solid-phase synthesis of boron carbides of heavy rare-earth elements using the hydride phase have been considered. Synthetic procedures with the use of carbon in the forms of carbon black and pyrographite were tested under atmospheric pressure, in medium and high vacuum. The obtained samples were characterized by X-ray and chemical (elemental) analyzes. A technique for obtaining compact samples of boron carbides of Ho, Tm, and Lu, which are homogeneous in the phase composition, has been developed.

Key words

boron carbides hydrides rare earth metals boron carbon solid phase synthesis 

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References

  1. 1.
    G. V. Samsonov, T. Ya. Kosolapova, G. G. Gnesin, V. B. Fedorus, L. G. Domasevitch, Karbidy i splavy na ih osnove [Carbides and Alloys on Their Basis], Naukova dumka, Kiev, 1976, 267 pp. (in Russian).Google Scholar
  2. 2.
    G. V. Samsonov, T. I. Serebryakova, V. A. Neronov, Boridy [Borides], Atomizdat, Moscow, 1975, 376 pp. (in Russian).Google Scholar
  3. 3.
    J. Hooper, Using Evolutionary Inspired Search Methodologies to Explore Polymorphism or Defect Associations in Materials Design, UOttawa, Ottawa, 2010, 292 pp.Google Scholar
  4. 4.
    K. Ohoyama, K. Kaneko, K. Indoh, H. Yamauchi, A. Tobo, H. Onodera, Y. Yamaguchi, J. Phys. Soc. Jpn, 2001, 70, 3291.CrossRefGoogle Scholar
  5. 5.
    V. Babizhetskyy, A. Simon, C. Hoch, K. Hiebl, L. Le Polles, R. Gautier, J.-F. Halet, J. Solid State Chem., 2012, 191, 121.CrossRefGoogle Scholar
  6. 6.
    Handbuchder Präparativen Anorganische Chemie, B. 4, Ed. G. Brauer, Verlag von Ferdinand Enke, 1978, 476 pp.Google Scholar
  7. 7.
    B. B. Damaskin, O. A. Petriy, B. I. Podlovchenko, V. A. Safonov, E. V. Stenina, N. V. Fedoroviych, Praktikum po electrokhimii [Practical Training in Electrochemistry], Vysshaya shkola, Moscow, 1991, 376 pp. (in Russian).Google Scholar
  8. 8.
    A. M. Dymov, Tekhnicheskiy analiz (control khimicheskogo sostava geleznih splavov) [Technical Analysis (Control of the Chemical Composition of Iron Alloys)], Metallurgiya, Moscow, 1954, 338 pp. (in Russian).Google Scholar
  9. 9.
    A. I. Busev, V. G. Tiptsova, V. M. Ivanov, Rukovodstvo po analiticheskoi khimii redkih elementov [Guide to the Analytical Chemistry of Rare Elements], Khimiya, Moscow, 1978, 432 pp. (in Russian).Google Scholar
  10. 10.
    M. G. Vasilieva, V. M. Lalykina, N. A. Makharashvili, A. L. Sokolova, V. M. Soifer, N. G. Tskiriya, in Analizy bora i ego neorganicheskih soedineniy [Analysis of Boron and Its Inorganic Compounds], Ed. E. E. Baroni, Atomizdat, Moscow, 1965, p. 268 (in Russian).Google Scholar

Copyright information

© Springer Science+Business Media, Inc. 2019

Authors and Affiliations

  1. 1.Bryansk State Academician I. G. Petrovskii UniversityBryanskRussian Federation
  2. 2.Peoples’ Friendship University of RussiaMoscowRussian Federation

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