Advertisement

Russian Chemical Bulletin

, Volume 68, Issue 8, pp 1542–1547 | Cite as

1,2-Bis(diphenylphosphino)ethane-containing commo-ferracarboranes of unusual structure

  • E. V. BalagurovaEmail author
  • F. M. Dolgushin
  • A. P. Tyurin
  • A. F. Smol’yakov
  • I. T. Chizhevsky
Full Article
  • 6 Downloads

Abstract

commo-Ferracarboranes Open image in new window and [8-{(nido-7″,8″-C2B9H11-9″(11″)-)Ph2PCH2CH2PPh2}-commo-3,3′-Fe-{1,2-C2H9B10}{1′2′-C2B9H11}] were prepared as minor products in the metallation reaction of [K]+[nido-7,8-C2B9H12] with the 14-electron iron complex [Ph2P(CH2)2PPh2]FeCl2. The structures of the complexes were determined by single-crystal X-ray diffraction.

Key words

commo-ferracarboranes 1,2-bis(diphenylphosphino)ethane ortho-cycloboro-nation molecular structure 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    A. P. Tyurin, F. M. Dolgushin, A. F. Smol’yakov, I. D. Grishin, D. I. D’yachihin, E. S. Turmina, D. F. Grishin, I. T. Chizhevsky, J. Organomet. Chem., 2013, 747, 148.CrossRefGoogle Scholar
  2. 2.
    Z. Janoušek, J. Plešek, S. Heřmánek, K. Baše, L. J. Todd, W. F. Wright, Coll. Czech. Chem. Commun., 1981, 46, 2818.CrossRefGoogle Scholar
  3. 3.
    J. E. Crook, N. N. Greenwood, J. D. Kennedy, W. S. McDonald, J. Chem. Soc., Chem. Commun., 1982, 383.Google Scholar
  4. 4.
    J. Bould, P. Brint, J. D. Kennedy, M. Thornton-Pett, J. Chem. Soc., Dalton Trans., 1993, 2335.Google Scholar
  5. 5.
    J. Bould, N. N. Greenwood, J. D. Kennedy, J. Chem. Soc., Dalton Trans., 1990, 1451.Google Scholar
  6. 6.
    M. Elrington, N. N. Greenwood, J. D. Kennedy, M. Thornton-Pett, J. Chem. Soc., Dalton Trans., 1986, 2277.Google Scholar
  7. 7.
    G. Ferguson, M. C. Jennings, A. J. Lough, S. Coughlan, T. R. Spalding, J. D. Kennedy, X. L. R. Fontaine, S. Stibr, J. Chem. Soc., Chem. Commun., 1990, 891.Google Scholar
  8. 8.
    G. Ferguson, F. R. Spalding, T. R. Spalding, Acta Crystallogr., 1988, C44, 1371.Google Scholar
  9. 9.
    J.-M. Dou, C.-H. Hu, W. Li, H.-J. Yao, R.-S. Jin, P.-J. Zheng, Polyhedron, 1997, 16, 2323.CrossRefGoogle Scholar
  10. 10.
    J. E. Crook, N. N. Greenwood, J. D. Kennedy, W. S. McDonald, J. Chem. Soc. Chem. Commun., 1981, 933.Google Scholar
  11. 11.
    G. A. Kukina, V. S. Sergienko, M. A. Porai-Koshits, Sov. J. Coord. Chem., 1985, 11, 234.Google Scholar
  12. 12.
    T. D. McGrath, A. Franken, J. A. Kautz, F. G. A. Stone, Inorg. Chem., 2005, 44, 8135.CrossRefGoogle Scholar
  13. 13.
    D. N. Cheredilin, R. Kadyrov, F. M. Dolgushin, E. V. Balagurova, I. A. Godovikov, S. P. Solodovnikov, I. T. Chizhevsky, Inorg. Chem. Commun., 2005, 8, 614.CrossRefGoogle Scholar
  14. 14.
    I. D. Grishin, D. I. D’yachihin, E. S. Turmina, F. M. Dolgushin, A. F. Smol’yakov, A. V. Piskunov, I. T. Chizhevsky, D. F. Grishin, J. Organometal. Chem., 2012, 721-722, 113.CrossRefGoogle Scholar
  15. 15.
    I. B. Sivaev, V. I. Bregadze, Collect. Czech. Chem. Commun., 1999, 64, 783.CrossRefGoogle Scholar
  16. 16.
    I. Rojo, F. Teixidor, R. Kivekäs, R. Sillanpää, C. Viñas, J. Am. Chem. Soc., 2003, 125, 14720.CrossRefGoogle Scholar
  17. 17.
    M. F. Hawthorne, J. N. Francis, Inorg. Chem., 1971, 10, 594.CrossRefGoogle Scholar
  18. 18.
    V. Šubrtová, K. Malý, V. Petříček, A. Línek, Acta Crystallogr. Sect. B, 1982, 38, 2028.CrossRefGoogle Scholar
  19. 19.
    I. B. Sivaev, V. I. Bregadze, J. Organomet. Chem., 2000, 614-615, 27.CrossRefGoogle Scholar
  20. 20.
    M. F. Hawthorne, D. C. Young, P. M. Garrett, D. A. Owen, S. G. Schwerin, F. N. Tebbe, P. A. Wegner, J. Am. Chem. Soc., 1968, 90, 862.CrossRefGoogle Scholar
  21. 21.
    D. J. Evans, P. B. Hitchcock, G. J. Leigh, B. K. Nicholson, A. C. Niedwieski, F. S. Nunes, J. F. Soares, Inorg. Chim. Acta., 2001, 319, 147.CrossRefGoogle Scholar
  22. 22.
    G. M. Sheldrick, SADABS, 1997, Bruker AXS Inc., Madison, WI-53719, USA.Google Scholar
  23. 23.
    A. L. Spek, Acta Cryst., 2015, C71, 9.Google Scholar
  24. 24.
    G. M. Sheldrick, Acta Cryst., 2015, C71, 3.Google Scholar

Copyright information

© Springer Science+Business Media, Inc. 2019

Authors and Affiliations

  • E. V. Balagurova
    • 1
    Email author
  • F. M. Dolgushin
    • 1
  • A. P. Tyurin
    • 2
  • A. F. Smol’yakov
    • 1
    • 3
  • I. T. Chizhevsky
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation
  2. 2.Gause Institute of New AntibioticsMoscowRussian Federation
  3. 3.Faculty of SciencePeoples’ Friendship University of Russia (RUDN University)MoscowRussian Federation

Personalised recommendations