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Russian Chemical Bulletin

, Volume 68, Issue 1, pp 121–124 | Cite as

Synthesis of chloro(organo)silylmethyl-o-carboranes from organochlorosilanes and bromomagnesiummethyl-o-carboranes

  • B. A. Izmaylov
  • V. A. Vasnev
  • G. D. MarkovaEmail author
Full Articles
  • 6 Downloads

Abstract

An efficient method for the synthesis of 1-chloro(dimethyl)silylmethyl-o-carborane, 1-dichloro(methyl)silylmethyl-o-carborane, 1-trichlorosilylmethyl-o-carborane, and 1-trichlorosilylmethyl- 2-methyl-o-carborane using 1-bromomagnesiummethyl-o-carborane, 1-bromomagnesiummethyl-2-methyl-o-carborane, and organochlorosilanes was developed.

Key words

Grignard reagent 1-bromomagnesiummethyl-o-carborane 1-bromo mag nesiummethyl-2-methyl-o-carborane dimethyldichlorosilane methyltrichlorosilane tetrachlorosilane 

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Copyright information

© Springer Science+Business Media, Inc. 2019

Authors and Affiliations

  • B. A. Izmaylov
    • 1
  • V. A. Vasnev
    • 1
  • G. D. Markova
    • 1
    Email author
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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