Advertisement

Russian Chemical Bulletin

, Volume 68, Issue 1, pp 110–115 | Cite as

High-energy 4(10)-2-fluoro-2,2-dinitroethyl and 4(10)-2,2-dinitropropyl derivatives of polynitrohexaazaisowurtzitanes

  • O. A. Luk′yanovEmail author
  • N. I. Shlykova
  • G. V. Pokhvisneva
  • T. V. Ternikova
  • K. A. Monogarov
  • D. B. Meerov
  • Yu. V. Nelyubina
  • P. V. Dorovatovskii
  • T. S. Kon′kova
Full Articles
  • 13 Downloads

Abstract

Methods for the syntheses of a series of high-energy 4(10)-2-fluoro-2,2-dinitroethyl and 4(10)-2,2-dinitroethyl derivatives of polynitrohexaazaisowurtzitanes were developed. The enthalpy of formation, molecular crystalline density, sensitivity to mechanical impact, and thermal stability were experimentally determined for two compounds.

Key words

4-(2-fluoro-2,2-dinitroethyl)-2,6,8,10,12-pentanitrohexaazaisowurtzitane 4-(2-fluoro-2,2-dinitroethyl)-10-(2,2,2-trinitroethyl)-2,6,8,12-tetranitrohexaazaisowurtzitane 4,10-bis(2-fluoro-2,2-dinitroethyl)-2,6,8,12-tetranitrohexaazaisowurtzitane 4-(2-fluoro-2,2- dinitroethyl)-10-(2,2-dinitropropyl)-2,6,8,12-tetranitrohexaazaisowurtzitane 4-(2,2-di nitropropyl)- 2,6,8,10,12-pentanitrohexaazaisowurtzitane 4-(2,2-dinitropropyl)-10-(2,2,2-tri nitroethyl)- 2,6,8,12-tetranitrohexaazaisowurtzitane 4,10-bis(2,2-dinitropropyl)-2,6,8,12-tetranitrohexaazaisowurtzitane enthalpy of formation density sensitivity to mechanical impact thermal stability 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    O. A. Luk´yanov, N. I. Shlykova, G. V. Pokhvisneva, T. V. Ternikova, S. V. Nikitin, G. A. Smirnov, Yu. V. Nelubina, P. V. Dorovatovsky, T. S. Kon´kova, N. V. Muravyev, A. N. Pivkina, Russ. Chem. Bull., 2017, 66, 1066.CrossRefGoogle Scholar
  2. 2.
    E. A. Miroshnichenko, T. S. Kon´kova, Ya. O. Inozemtsev, Yu. N. Matyushin, Russ. Chem. Bull., 2010, 59, 890.CrossRefGoogle Scholar
  3. 3.
    V. V. Pepekin, Yu. N. Matyushin, G. G. Rozantsev, S. A. Shevelev, A. Ya. Apin, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1972, 21, 2634.CrossRefGoogle Scholar
  4. 4.
    STANAG 4489, Explosives, Impact Sensitivity Tests, NATO, Brussels, 1999.Google Scholar
  5. 5.
    STANAG 4489, Explosives, Friction Sensitivity Tests, NATO, Brussels, 2002.Google Scholar
  6. 6.
    N. V. Muravyev, K. A. Monogarov, A. A. Bragin, I. V. Fomenkov, A. N. Pivkina, Thermochim. Acta, 2016, 631, 1.CrossRefGoogle Scholar
  7. 7.
    G. M. Shedrick, Acta Cristallogr., 2008, A64, 112.Google Scholar

Copyright information

© Springer Science+Business Media, Inc. 2019

Authors and Affiliations

  • O. A. Luk′yanov
    • 1
    Email author
  • N. I. Shlykova
    • 1
  • G. V. Pokhvisneva
    • 1
  • T. V. Ternikova
    • 1
  • K. A. Monogarov
    • 2
  • D. B. Meerov
    • 2
  • Yu. V. Nelyubina
    • 3
  • P. V. Dorovatovskii
    • 4
  • T. S. Kon′kova
    • 2
  1. 1.N. D. Zelinsky Institute of Organic ChemistryRussian Academy of SciencesMoscowRussian Federation
  2. 2.N. N. Semenov Institute of Chemical PhysicsRussian Academy of SciencesMoscowRussian Federation
  3. 3.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation
  4. 4.Russian Research Centre “Kurchatov Institute,”MoscowRussian Federation

Personalised recommendations