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Russian Chemical Bulletin

, Volume 67, Issue 12, pp 2282–2289 | Cite as

Synthesis of telehelic oligodimethylsiloxanes with 4-carboxypyrrolidone fragments: rheological and thermal properties

  • V. V. GorodovEmail author
  • A. V. Bakirov
  • M. I. Buzin
  • V. G. Vasil´ev
  • D. I. Shragin
  • V. D. Myakushev
  • V. S. Papkov
  • S. N. Chvalun
  • A. M. Muzafarov
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Abstract

Telehelic oligodimethylsiloxanes containing 4-carboxypyrrolidone fragments were synthesized by the reactions of oligodimethylsiloxanes bearing terminal 3-aminopropyl groups with itaconic acid. The thermal and rheological properties of the obtained polymers were studied. The activation energies of viscous flow of the oligomers obtained and the previously synthesized oligodimethylsiloxanes containing terminal fragments of undecenoic or benzoic acid are compared.

Key words

carboxyl-containing polymers polydimethylsiloxanes aminosiloxanes pyrrolidone itaconic acid 

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • V. V. Gorodov
    • 1
    • 2
    Email author
  • A. V. Bakirov
    • 1
    • 3
  • M. I. Buzin
    • 2
    • 4
  • V. G. Vasil´ev
    • 2
  • D. I. Shragin
    • 1
    • 2
  • V. D. Myakushev
    • 1
  • V. S. Papkov
    • 2
  • S. N. Chvalun
    • 1
    • 3
  • A. M. Muzafarov
    • 1
    • 2
  1. 1.N. S. Enikolopov Institute of Polymeric MaterialsRussian Academy of SciencesMoscowRussian Federation
  2. 2.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation
  3. 3.Research Center “Kurchatov Institute,”MoscowRussian Federation
  4. 4.V. I. Lenin Moscow Pedagogical State UniversityMoscowRussian Federation

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