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Russian Chemical Bulletin

, Volume 67, Issue 12, pp 2271–2274 | Cite as

Condensation products of Betti base and pyridinecarboxaldehydes

  • K. E. Metlushka
  • D. N. Sadkova
  • K. A. Nikitina
  • Z. R. Yamaleeva
  • K. A. Ivshin
  • O. N. Kataeva
  • V. A. AlfonsovEmail author
Full Articles
  • 9 Downloads

Abstract

Previously unknown condensation products were obtained by the reaction of the racemic Betti base with 2-, 3- and 4-pyridinecarboxaldehydes. It was established that they have a naphthoxazine structure in solid state. In the solution, a three-component ring-chain equilibrium is established between the imine form and cis- and trans-oxazines. Over time or under heating, these compounds are prone to 2-azaallylic prototropic tautomerism, involving 1-(phenyl- (pyridinylmethylimino)methyl)naphthalen-2-ols in equilibrium.

Key words

Betti base pyridinecarboxaldehydes condensation reactions imines oxazines 2-azaallylic prototropic tautomerism 

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • K. E. Metlushka
    • 1
  • D. N. Sadkova
    • 1
  • K. A. Nikitina
    • 1
  • Z. R. Yamaleeva
    • 1
  • K. A. Ivshin
    • 1
    • 2
  • O. N. Kataeva
    • 1
  • V. A. Alfonsov
    • 1
    Email author
  1. 1.Arbuzov Institute of Organic and Physical ChemistryFederal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”KazanRussian Federation
  2. 2.Alexander Butlerov Institute of ChemistryKazan Federal UniversityKazanRussian Federation

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