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Russian Chemical Bulletin

, Volume 67, Issue 12, pp 2164–2171 | Cite as

Reactivity of an aluminum hydride complex with a redox-active diimine ligand

  • V. G. Sokolov
  • T. S. Koptseva
  • V. A. Dodonov
  • R. V. Rumyantsev
  • I. L. FedushkinEmail author
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Abstract

The reaction of the hydride [(dpp-bian)Al(H)Cl] (1) containing the 1,2-bis[(2,6-diisopropylphenyl) imino]acenaphthene (dpp-bian) radical anion with MeLi affords the compound [(dpp-bian)Al(H)Me] (2). The reaction of complex 1 with two equivalents of PhC≡CNa involves the replacement of chlorine along with oxidative substitution of hydrogen accompanied by the reduction of dpp-bian to the dianion to form the compound [(dpp-bian)Al(C≡CPh)2Na(Et2O)2] ({sn3}). This reaction gives the complex [{dpp-bian(H)}Al(C≡CPh)3Na(Et2O)2] (4) as the second product, which is apparently generated in the reaction of compound 3 with PhC≡CH. The reaction of compound 1 with Cp*Na (Cp* is pentamethylcyclopentadiene) in dimethoxyethane is also accompanied by the reduction of redox-active dpp-bian to the dianion, giving the complex [(dpp-bian)Al(H)Cl][Na(DME)3] (5). Diamagnetic derivatives 3–5 were characterized by 1H NMR spectroscopy; paramagnetic compound 2, by EPR spectroscopy. The molecular structures of compounds 2–5 were determined by X-ray diffraction.

Key words

aluminum hydrides redox-active ligands diimine ligands molecular structure 
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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • V. G. Sokolov
    • 1
  • T. S. Koptseva
    • 1
  • V. A. Dodonov
    • 1
  • R. V. Rumyantsev
    • 1
  • I. L. Fedushkin
    • 1
    Email author
  1. 1.G. A. Razuvaev Institute of Organometallic ChemistryRussian Academy of SciencesNizhny NovgorodRussian Federation

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