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Russian Chemical Bulletin

, Volume 67, Issue 11, pp 2088–2097 | Cite as

Synthesis of amphiphilic V-type silica nanogels and study of their self-assembling at the air–water interface

  • V. V. Kazakova
  • O. B. Gorbatsevich
  • Yu. N. Malakhova
  • A. I. Buzin
  • A. M. Muzafarov
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Abstract

The methods for the synthesis of silica nanogels and a modifying agent, as well as related amphiphilic V-type silica nanogels are presented. Self-assembly of the synthesized amphi philic nanogels during the formation of Langmuir monolayers at the air–water interface is considered. Aggregate structures were revealed to form during ordering of the silica V-type nanogels at the air–water interface after collapse of the Langmuir monolayer. For the low-molecular-weight fraction of the silica nanogels, the aggregates do not completely decompose upon the expansion of the Langmuir layer since are formed by mutually penetrating macromolecules. For the highmolecular- weight fraction, they are reversibly formed and decompose in consecutive compression– expansion cycles, which is characteristic of Langmuir layers of nanoparticles.

Key words

nanogels silica nanoparticles Langmuir–Blodgett films self-assembly of amphiphilic macromolecules 

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • V. V. Kazakova
    • 1
  • O. B. Gorbatsevich
    • 1
  • Yu. N. Malakhova
    • 2
    • 3
  • A. I. Buzin
    • 1
  • A. M. Muzafarov
    • 1
    • 4
  1. 1.N. S. Enikolopov Institute of Synthetic Polymeric MaterialsRussian Academy of SciencesMoscowRussian Federation
  2. 2.MIREA – Russian Technological UniversityM. V. Lomonosov Institute of Fine Chemical TechnologyMoscowRussian Federation
  3. 3.National Research Centre “Kurchatov Institute,”MoscowRussian Federation
  4. 4.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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