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Russian Chemical Bulletin

, Volume 67, Issue 10, pp 1891–1898 | Cite as

Synthesis and structure of 6-azido-2,4-bis(2,2,2-trinitroethylamino)-1,3,5-triazine and its N-nitro derivatives

  • A. G. Korepin
  • A. V. Shastin
  • G. V. Lagodzinskaya
  • G. V. Shilov
  • D. V. Korchagin
  • N. M. Glushakova
  • V. S. Malygina
  • V. P. Kosilko
  • V. P. Lodygina
  • S. M. Aldoshin
Article
  • 13 Downloads

Abstract

Methods were developed for the synthesis of 6-azido-2,4-bis(2,2,2-trinitroethylamino)- 1,3,5-triazine and its N-nitro derivatives (6-azido-2,4-bis(2,2,2-trinitroethyl)nitramino-1,3,5-triazine and 6-azido-2-(2,2,2-trinitroethylamino)-4-(2,2,2-trinitroethyl)nitramino-1,3,5-triazine) containing combinations of azido, trinitroethyl, and nitramine groups. These compounds are of interest as components of energetic composites. The molecular and crystal structures of 6-azido-2,4-bis(2,2,2-trinitroethylamino)-1,3,5-triazine and 6-azido-2,4-bis(2,2,2-trinitroethyl) nitramino-1,3,5-triazine were studied by X-ray diffraction and NMR spectroscopy.

Key words

6-azido-2,4-bis(2,2,2-trinitroethylamino)-1,3,5-triazine 6-azido-2,4-bis(2,2,2-trinitroethyl)nitramino-1,3,5-triazine synthesis trinitroethylation N-nitration X-ray diffraction NMR spectroscopy 

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • A. G. Korepin
    • 1
  • A. V. Shastin
    • 1
  • G. V. Lagodzinskaya
    • 1
  • G. V. Shilov
    • 1
  • D. V. Korchagin
    • 1
  • N. M. Glushakova
    • 1
  • V. S. Malygina
    • 1
  • V. P. Kosilko
    • 1
  • V. P. Lodygina
    • 1
  • S. M. Aldoshin
    • 1
  1. 1.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovkaMoscow RegionRussian Federation

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