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Russian Chemical Bulletin

, Volume 67, Issue 7, pp 1190–1195 | Cite as

Role of macrocyclic effect in complex formation of palladium(II) with ligands anchored on a solid support

  • T. M. Buslaeva
  • N. M. Bodnar
  • S. P. Gromov
  • E. V. Kopylova
  • G. V. Lisichkin
  • H. V. Ehrlich
Article
  • 14 Downloads

Abstract

The method for grafting dithiacrown ether and its linear analogue to the silica surface using preliminary prepared organosilicon derivative is developed. The importance of the acylation step in the process of grafting is underlined. The acylation is required to prevent sorption of platinum metals complex anions by the anion exchange mechanism, the probability of which increases due to protonation of the spacer in an acidic medium. The interaction of palladium(II) with anchored ligands in hydrochloric acid media was studied in details. The comparative study of two sorbents revealed that the macrocyclic effect plays a negligible role in binding of palladi um(II) ions. Therefore, linear ligands are preferred for the development of sorbents for molecular recognition of platinum metals ions.

Key words

macrocyclic effect dithiacrown ethers molecular recognition palladium(II) sorption complex formation modified silica 

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • T. M. Buslaeva
    • 1
  • N. M. Bodnar
    • 1
  • S. P. Gromov
    • 2
  • E. V. Kopylova
    • 3
  • G. V. Lisichkin
    • 4
  • H. V. Ehrlich
    • 4
  1. 1.Moscow Techological University (M. V. Lomonosov Institute of Fine Chemical Technologies)MoscowRussian Federation
  2. 2.Photochemistry Center of the Russian Academy of SciencesMoscowRussian Federation
  3. 3.Moscow Techological University (Institute of Physics and Technology)MoscowRussian Federation
  4. 4.Department of ChemistryM. V. Lomonosov Moscow State UniversityMoscowRussian Federation

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