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Disperse aqueous systems based on (S)-lysine in a wide range of concentrations and physiologically important temperatures

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Abstract

It was shown for the first time using a complex of physicochemical methods (dynamic and electrophoretic light scattering, nanoparticle tracking analysis, transmission electron and atomic force microscopy, conductometry, pH-metry) that in a temperature range of 25—60 °С (S)-lysine aqueous solutions (1•10–17—1•10–2 mol L–1) are disperse systems, where the nature and parameters of the disperse phase change with dilution, which affects the nonmonotonic dependences of the specific conductivity and pH of the system. Nanoassociates hundreds of nanometers in size were found to contain ordered water structures that are responsible for the size and ζ-potential of the disperse phase in the aqueous systems and also participate in the formation of spatially organized systems on the support.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    I. S. Ryzhkina, S. Yu. Sergeeva, L. I. Murtazina, L. R. Sabirzyanova, M. D. Shevelev, M. K. Kadirov & A. I. Konovalov

  2. Kazan National Research Technological University, 68 ul. K. Marksa, 420015, Kazan, Russian Federation

    R. A. Safiullin

  3. A. M. Butlerov Chemical Institute, Kazan (Volga Region) Federal University, 18 ul. Kremlevskaya, 420008, Kazan, Russian Federation

    M. D. Shevelev

Authors
  1. I. S. Ryzhkina
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  2. S. Yu. Sergeeva
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  3. R. A. Safiullin
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  4. L. I. Murtazina
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  5. L. R. Sabirzyanova
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  6. M. D. Shevelev
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  7. M. K. Kadirov
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  8. A. I. Konovalov
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Corresponding author

Correspondence to I. S. Ryzhkina.

Additional information

Dedicated to Academician of the Russian Academy of Sciences G. A. Abakumov on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1691—1698, September, 2017.

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Ryzhkina, I.S., Sergeeva, S.Y., Safiullin, R.A. et al. Disperse aqueous systems based on (S)-lysine in a wide range of concentrations and physiologically important temperatures. Russ Chem Bull 66, 1691–1698 (2017). https://doi.org/10.1007/s11172-017-1942-1

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  • DOI: https://doi.org/10.1007/s11172-017-1942-1

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