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Russian Chemical Bulletin

, Volume 66, Issue 9, pp 1691–1698 | Cite as

Disperse aqueous systems based on (S)-lysine in a wide range of concentrations and physiologically important temperatures

  • I. S. Ryzhkina
  • S. Yu. Sergeeva
  • R. A. Safiullin
  • L. I. Murtazina
  • L. R. Sabirzyanova
  • M. D. Shevelev
  • M. K. Kadirov
  • A. I. Konovalov
Full Articles

Abstract

It was shown for the first time using a complex of physicochemical methods (dynamic and electrophoretic light scattering, nanoparticle tracking analysis, transmission electron and atomic force microscopy, conductometry, pH-metry) that in a temperature range of 25—60 °С (S)-lysine aqueous solutions (1•10–17—1•10–2 mol L–1) are disperse systems, where the nature and parameters of the disperse phase change with dilution, which affects the nonmonotonic dependences of the specific conductivity and pH of the system. Nanoassociates hundreds of nanometers in size were found to contain ordered water structures that are responsible for the size and ζ-potential of the disperse phase in the aqueous systems and also participate in the formation of spatially organized systems on the support.

Key words

(S)-lysine aqueous disperse system low concentrations temperature nanoassociates domains nonmonotonic dependences physicochemical properties 

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References

  1. 1.
    A. I. Konovalov, I. S. Ryzhkina, Russ. Chem. Bull. (Int. Ed.), 2014, 63, 1.CrossRefGoogle Scholar
  2. 2.
    A. I. Konovalov, I. S. Ryzhkina, Geochem. Int., 2014, 52, 1207.CrossRefGoogle Scholar
  3. 3.
    M. Sedlák, J. Phys. Chem. B, 2006, 110, 4329.CrossRefGoogle Scholar
  4. 4.
    M. Sedlák, D. Rak, J. Phys. Chem. B, 2013, 117, 2499.CrossRefGoogle Scholar
  5. 5.
    L. O. Kononov, RSC Adv., 2015, 5, 46718.CrossRefGoogle Scholar
  6. 6.
    I. V. Lunev, A. A. Khamzin, I. I. Popov, M. N. Ovchinnikov, I. S. Ryzhkina, O. A. Mishina, Yu. V. Kiseleva, A. I. Konovalov, Dokl. Phys. Chem., 2014, 455, 56; DOI: 10.1134/s0012501614060013.CrossRefGoogle Scholar
  7. 7.
    I. S. Ryzhkina, Yu. V. Kiseleva, O. A. Mishina, L. I. Murtazina, A. I. Litvinov, M. K. Kadirov, A. I. Konovalov, Russ. Chem. Bull. (Int. Ed.), 2015, 64, 579.CrossRefGoogle Scholar
  8. 8.
    D. Hagmeyer, J. Ruesing, T. Fenske, H.-W. Klein, C. Schmuck, W. Schrader, M. E. M. da Piedade, M. Epple, RSC Adv., 2012, 2, 4690.CrossRefGoogle Scholar
  9. 9.
    I. S. Ryzhkina, S. Yu. Sergeeva, R. A. Safiullin, S. A. Ryzhkin, A. B. Margulis, L. I. Murtazina, A. P. Timosheva, A. V. Chernova, M. K. Kadirov, A. I. Konovalov, Russ. Chem. Bull. (Int. Ed.), 2016, 65, 1505.CrossRefGoogle Scholar
  10. 10.
    D. A. Konovalov, L. I. Murtazina, I. S. Ryzhkina, A. I. Konovalov, Dokl. Phys. Chem., 2015, 463, 154.CrossRefGoogle Scholar
  11. 11.
    V. I. Lobyshev, Ros. Khim. Zh., 2007, 51, No. 1, 107 (in Russian).Google Scholar
  12. 12.
    S. M. Pershin, A. F. Bunkin, M. Ya. Grishin, M. A. Davydov, V. N. Lednev, N. P. Pal´mina, A. N. Fedorov, Dokl. Phys. Chem., 2015, 461, 114.CrossRefGoogle Scholar
  13. 13.
    L. N. Gall´, N. R. Gall´, Dokl. Phys. Chem., 2015, 461, 92.CrossRefGoogle Scholar
  14. 14.
    T. A. Yinnon, Z. Q. Liu, Water, 2015, 7, 70.Google Scholar
  15. 15.
    I. S. Ryzhkina, S. Yu. Sergeeva, E. M. Masagutova, L. I. Murtazina, O. A. Mishina, A. P. Timosheva, V. V. Baranov, A. N. Kravchenko, A. I. Konovalov, Russ. Chem. Bull. (Int. Ed.), 2015, 64, 2125.CrossRefGoogle Scholar
  16. 16.
    I. S. Ryzhkina, Yu. V. Kiseleva, L. I. Murtazina, O. A. Mishina, A. P. Timosheva, S. Yu. Sergeeva, V. V. Baranov, A. N. Kravchenko, A. I. Konovalov, Mendeleev Commun., 2015, 25, 72.CrossRefGoogle Scholar
  17. 17.
    H. D. Yakubke, H. Yescheit, Aminosauren, Peptide, Proteine, AkademieVerlag, Berlin, 1981.Google Scholar
  18. 18.
    G. Kubin´i, Ros. Khim. Zh., 2006, 50, No. 2, 5 (in Russian).Google Scholar
  19. 19.
    L. A. Sever´yanova, M. E. Dolgintsev, Kurskii Nauchnopraktich. Vestn. "Chelovek i ego zdorov´e" [Kursk Scientific Practical Bulletin "Man and his Health"], 2007, No. 2, 67 (in Russian).Google Scholar
  20. 20.
    A. A. Kurtseva, M. Yu. Smakhtin, A. V. Ivanov, A. V. Besedin, Kurskii Nauchno-praktich. Vestn. "Chelovek i ego zdorov´e" [Kursk Scientific Practical Bulletin "Man and his Health"], 2008, No. 3, 5 (in Russian).Google Scholar
  21. 21.
    R. Griffith, D. Walsh, K. Myrtel, R. Thompson, A. Behforooz, Dermatologica, 1987, 175, 183.CrossRefGoogle Scholar
  22. 22.
    S. E. Kondakov, M. Ya. Mel´nikov, O. S. Prokoptseva, Dokl. Phys. Chem., 2014, 455, 45.CrossRefGoogle Scholar
  23. 23.
    I. S. Ryzhkina, Yu. V. Kiseleva, O. A. Mishina, A. P. Timosheva, S. Yu. Sergeeva, A. N. Kravchenko, A. I. Konovalov, Mendeleev Commun., 2013, 23, 262.CrossRefGoogle Scholar
  24. 24.
    A. Konovalov, I. Ryzhkina, E. Maltzeva, L. Murtazina, Yu. Kiseleva, V. Kasparov, N. Palmina, Electromagn. Biol. Med., 2015, 34, 141.CrossRefGoogle Scholar
  25. 25.
    V. I. Usenko, I. S. Ryzhkina, S. Yu. Sergeeva, D. E. Dordzhieva, M. R. Bektemirova, Veterinarnyi Vrach [Veterinarian], 2016, No. 5, 21 (in Russian).Google Scholar
  26. 26.
    A. I. Konovalov, I. S. Ryzhkina, N. P. Pal´mina, E. L. Mal´tzeva, S. Yu. Sergeeva, L. I. Murtazina, O. A. Salakhutdinova, M. D. Shevelev, V. E. Zhernovkov, Dokl. Phys. Chem., 2017, 474, 80.CrossRefGoogle Scholar
  27. 27.
    I. A. Yamskov, V. P. Yamskova, A. N. Danilenko, Z. S. Klemenkova, B. G. Antipov, F. R. Chernikov, M. M. Gusynina, E. Yu. Rybakova, Ros. Khim. Zh., 1999, 43, No. 5, 34 (in Russian).Google Scholar
  28. 28.
    E. B. Burlakova, A. A. Konradov, E. L. Mal´tzeva, Khim. Fiz., 2003, 22, No. 2, 21 (in Russian).Google Scholar
  29. 29.
    A. Lo, J. Cardarella, J. Turner, S. Y. Lo, Forum on Immunopath. Dis.Ther., 2012, 3, 237.CrossRefGoogle Scholar
  30. 30.
    M. W. Ho, Water, 2014, 6, 1.Google Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2017

Authors and Affiliations

  • I. S. Ryzhkina
    • 1
  • S. Yu. Sergeeva
    • 1
  • R. A. Safiullin
    • 2
  • L. I. Murtazina
    • 1
  • L. R. Sabirzyanova
    • 1
  • M. D. Shevelev
    • 1
    • 3
  • M. K. Kadirov
    • 1
  • A. I. Konovalov
    • 1
  1. 1.A. E. Arbuzov Institute of Organic and Physical ChemistryKazan Scientific Center of the Russian Academy of SciencesKazanRussian Federation
  2. 2.Kazan National Research Technological UniversityKazanRussian Federation
  3. 3.A. M. Butlerov Chemical Institute, Kazan (Volga Region) Federal UniversityKazanRussian Federation

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