Russian Chemical Bulletin

, Volume 66, Issue 9, pp 1675–1685 | Cite as

Synthesis of thioether-containing carbosilane dendrimers with sterically shielded sulfur atoms

  • А. N. TarasenkovEmail author
  • E. V. Getmanova
  • E. A. Tatarinova
  • М. I. Buzin
  • N. V. Demchenko
  • G. V. Cherkaev
  • А. М. Muzafarov
Full Articles


Carbosilane thiols were synthesized as the first- and second-generation (in silicon) dendrons. It was demonstrated that the resulting bulky thiols successfully undergo the thiol—ene addition to third-generation polyallyl carbosilane dendrimer as a photoinitiated radical reaction to give the corresponding thioether-containing derivatives with sterically shielded sulfur atoms.

Key words

hydrothiolation thiol—ene addition carbosilane monodendron carbosilane dendrimer UV radiation 


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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2017

Authors and Affiliations

  • А. N. Tarasenkov
    • 1
    Email author
  • E. V. Getmanova
    • 1
  • E. A. Tatarinova
    • 1
  • М. I. Buzin
    • 2
  • N. V. Demchenko
    • 1
  • G. V. Cherkaev
    • 1
  • А. М. Muzafarov
    • 2
  1. 1.N. S. Enikolopov Institute of Synthetic Polymer MaterialsRussian Academy of SciencesMoscowRussian Federation
  2. 2.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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