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Russian Chemical Bulletin

, Volume 66, Issue 1, pp 47–55 | Cite as

Photoprocesses in N-ammonioalkyl derivatives of azacrown-containing styryl dyes and their complexes with metal perchlorates

  • L. S. Atabekyan
  • N. A. Lobova
  • A. I. Vedernikov
  • V. G. Avakyan
  • S. P. Gromov
  • A. K. Chibisov
Full Articles
  • 39 Downloads

Abstract

Photophysical processes and photochemical reactions in the N-ammonioalkyl derivatives of the azacrown-containing styryl dyes and their complexes with lead and barium perchlorates in MeCN and CH2Cl2 were studied by 1Н NMR spectroscopy, absorption spectroscopy, luminescence spectroscopy, laser kinetic spectroscopy, and quantum chemistry. Molecules of the styryl dyes and their complexes are able to undergo normal (fast) and delayed fluorescence and trans–cis-photoisomerization. The molecules in the triplet state participate in degradation processes of the electron excitation energy.

Keywords

delayed fluorescence triplet state dimerization cycloaddition 

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Copyright information

© Springer Science+Business Media, LLC 2017

Authors and Affiliations

  • L. S. Atabekyan
    • 1
  • N. A. Lobova
    • 1
  • A. I. Vedernikov
    • 1
  • V. G. Avakyan
    • 1
  • S. P. Gromov
    • 1
    • 2
  • A. K. Chibisov
    • 1
  1. 1.Center of PhotochemistryRussian Academy of SciencesMoscowRussian Federation
  2. 2.Department of ChemistryM. V. Lomonosov Moscow State UniversityMoscowRussian Federation

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