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Russian Chemical Bulletin

, Volume 65, Issue 11, pp 2757–2759 | Cite as

Oligomerization of higher olefins and alkylation of toluene catalyzed by 2-[hydroxy(diaryl)methyl]-8-hydroxyquinoline oxovanadium(v) complexes

  • N. A. Kolosov
  • V. A. Tuskaev
  • S. Ch. Gagieva
  • O. V. Polyakova
  • A. I. Sizov
  • B. M. BulychevEmail author
Brief Communications
  • 47 Downloads

Abstract

New oxovanadium(V) complexes with 2-[hydroxy(diaryl)methyl]-8-hydroxyquinoline ligands were synthesized. These compounds were found to be efficient tandem catalysts of oligomerization of hex-1-ene and alkylation of toluene, which leads to the mixture of hexyl-, dihexyl-, and trihexyltoluenes with the conversion of the starting alkene more than 99%.

Key words

vanadium complexes organoaluminum compounds tandem catalysis hex-1-ene toluene oligomerization alkylation 

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Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  • N. A. Kolosov
    • 1
  • V. A. Tuskaev
    • 1
    • 2
  • S. Ch. Gagieva
    • 1
  • O. V. Polyakova
    • 1
  • A. I. Sizov
    • 1
  • B. M. Bulychev
    • 1
    Email author
  1. 1.Department of ChemistryM. V. Lomonosov Moscow State UniversityMoscowRussian Federation
  2. 2.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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