Russian Chemical Bulletin

, Volume 65, Issue 4, pp 1116–1118 | Cite as

Surface modification of epoxy resin by amphiphilic fluoroorganosiloxane copolymers

  • M. A. Soldatov
  • A. V. Naumkin
  • A. Yu. Pereyaslavtsev
  • O. A. Serenko
  • A. I. PertsinEmail author
Full Articles


An amphiphilic fluoroorganosiloxane copolymer designed for a surface modification of epoxy resin by fluorine-containing fragments has been synthesized. The copolymer contains anchor units with terminal amino groups forming chemical bonds with the epoxy matrix. The composition of the surface layers as a function of the content of the copolymer modifier has being studied by the XPS method. The presence of anchor units affects the degree of segregation and the concentration profile of the fluorocontaining groups in depth.


surface modification fluoroorganosiloxane copolymers X-ray photoelectron spectroscopy 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    D. R. Iyengar, S. M. Perutz, C.-A. Dai, C. K. Ober, E. J. Kramer, Macromolecules, 1996, 29, 1229.CrossRefGoogle Scholar
  2. 2.
    M. A. Soldatov, N. A. Sheremetéva, A. A. Kalinina, N. V. Demchenko, O. A. Serenko, A. M. Muzafarov, Russ. Chem. Bull. (Int. Ed.), 2014, 63, 267 [Izv. Akad. Nauk, Ser. Khim., 2014, 267].CrossRefGoogle Scholar
  3. 3.
    A. V. Naumkin, M. A. Soldatov, D. R. Strel´tsov, A. Yu. Pereyaslavtsev, I. O. Volkov, A. I. Pertsin, Russ. Chem. Bull. (Int. Ed.), 2016, 65, 1072 [Izv. Akad. Nauk, Ser. Khim., 2016, 1072].Google Scholar
  4. 4.
    Practical Surface Analysis by Auger and X-ray Photoelectron Spectroscopy, Eds D. Briggs, M. P. Seah, John Wiley and Sons, Chichester, 1983, 533 pp.Google Scholar

Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  • M. A. Soldatov
    • 1
  • A. V. Naumkin
    • 2
  • A. Yu. Pereyaslavtsev
    • 3
  • O. A. Serenko
    • 2
  • A. I. Pertsin
    • 2
    Email author
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation
  2. 2.N. S. Enikolopov Institute of Synthetic Polymer MaterialsRussian Academy of SciencesMoscowRussian Federation
  3. 3.N. L. Dukhov All-Russian Research Institute of AutomaticsMoscowRussian Federation

Personalised recommendations