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Russian Chemical Bulletin

, Volume 65, Issue 4, pp 1013–1019 | Cite as

Synthesis of dimethylcyclosiloxanes in the active medium

  • A. A. Kalinina
  • E. V. Talalaeva
  • A. I. Demchenko
  • N. G. Vasilenko
  • Yu. A. Molodtsova
  • N. V. Demchenko
  • A. M. Muzafarov
Full Articles

Abstract

The process of condensation of dimethyldiethoxysilane in the active medium in a presence of acetyl chloride, trifluoroacetic acid, and sulfocationites has been investigated. Their impact on the rate and selectivity of the process has been estimated. The prospects of the application of sulfocationites for the polycondensation of dimethyldiethoxysilane in anhydrous acetic acid with an 99% yield have been demonstrated.

Keywords

polycondensation alkoxysilane cyclosiloxane active medium 

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Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  • A. A. Kalinina
    • 1
    • 2
  • E. V. Talalaeva
    • 1
  • A. I. Demchenko
    • 3
  • N. G. Vasilenko
    • 1
  • Yu. A. Molodtsova
    • 2
  • N. V. Demchenko
    • 1
  • A. M. Muzafarov
    • 1
    • 2
  1. 1.N. S. Enikolopov Institute of Synthetic Polymeric MaterialsRussian Academy of SciencesMoscowRussian Federation
  2. 2.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation
  3. 3.State Research Institute for Chemistry and Technology of Organoelement CompoundsMoscowRussian Federation

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