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New chiral CuII complexes and their catalytic activity in enantioselective Henry reaction

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Abstract

New chiral polydentante ligands capable of complexation of Cu2+ ions were synthesized using readily available derivatives of (S)-proline, d-glyceraldehyde, and imidazole as the starting materials. The synthesized complexes are efficient catalysts for enantioselective nitroaldol condensation (the Henry reaction).

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    V. V. Veselovsky & M. V. Zlokazov

Authors
  1. V. V. Veselovsky
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  2. M. V. Zlokazov
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Correspondence to V. V. Veselovsky.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 0440—0444, February, 2016.

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Veselovsky, V.V., Zlokazov, M.V. New chiral CuII complexes and their catalytic activity in enantioselective Henry reaction. Russ Chem Bull 65, 440–444 (2016). https://doi.org/10.1007/s11172-016-1318-y

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  • DOI: https://doi.org/10.1007/s11172-016-1318-y

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