Russian Chemical Bulletin

, Volume 64, Issue 11, pp 2663–2666 | Cite as

Synthesis and structure of new dinitrosyl iron complexes with bridging thiolate ligands [Fe2(μ-SR)2(NO)4]

  • P. B. Davidovich
  • V. V. Gurzhiy
  • A. V. Garabadzhiu
  • A. N. Belyaev
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  • 23 Downloads

Abstract

Two new dinitrosyl iron complexes with bridging thiolate ligands [Fe2(µ-SR)2(NO)4], where R = n-Hex or cyclo-Hex, were synthesized and their molecular structures were analyzed. The structure of the [Fe2(µ-S-n-Hex)2(NO)4] complex was determined by X-ray diffraction. For the [Fe2(µ-S-cyclo-Hex)2(NO)4] complex, the geometry was assigned based on the results of structure-sensitive spectroscopic methods and DFT quantum chemical calculations.

Key words

binuclear iron thiolate complexes dinitrosyl complexes X-ray diffraction study DFT calculations 

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Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • P. B. Davidovich
    • 1
  • V. V. Gurzhiy
    • 2
  • A. V. Garabadzhiu
    • 1
  • A. N. Belyaev
    • 1
  1. 1.St. Petersburg State Technological InstituteSt. PetersburgRussian Federation
  2. 2.St. Petersburg State UniversitySt. PetersburgRussian Federation

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