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Russian Chemical Bulletin

, Volume 64, Issue 10, pp 2498–2504 | Cite as

Synthesis of alkoxybenzylmethylsilanes and polybenzylmethylsiloxane polymers on their basis

  • S. A. Milenin
  • A. A. Kalinina
  • V. V. Gorodov
  • N. G. Vasilenko
  • M. I. Buzin
  • A. M. Muzafarov
Article

Abstract

An efficient solvent-free procedure for the preparation of alkoxybenzylmethylsilanes by organomagnesium synthesis was developed. The reaction conditions gave the high yields of the target products. A number of benzylmethylsiloxane polymers was synthesized by polycondensation of alkoxybenzylmethylsilanes in anhydrous acetic acid. The products obtained can become a good alternative to phenylsiloxanes in some practical applications.

Keywords

organoalkoxysilanes organomagnesium synthesis alkoxybenzylmethylsilanes polycondensation polybenzylmethylsiloxanes 

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Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • S. A. Milenin
    • 1
  • A. A. Kalinina
    • 1
  • V. V. Gorodov
    • 1
  • N. G. Vasilenko
    • 1
  • M. I. Buzin
    • 2
  • A. M. Muzafarov
    • 1
    • 2
  1. 1.N. S. Enikolopov Institute of Synthetic Polymeric MaterialsRussian Academy of SciencesMoscowRussian Federation
  2. 2.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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