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Russian Chemical Bulletin

, Volume 64, Issue 9, pp 2145–2151 | Cite as

Rheological properties of nonfunctional derivatives of hyperbranched polycarbosilanes

  • N. A. Sheremetyeva
  • V. G. Vasiliev
  • V. S. Papkov
  • G. G. Pak
  • V. D. Myakushev
  • E. Yu. KramarenkoEmail author
  • A. M. Muzafarov
Full Articles

Abstract

The rheological properties of melts of nonfunctional hyperbranched polycarbosilane polymers differed in regularity of the structure and chain length between the branch points were studied for the first time. Unlike melts of linear polymers, the studied hyperbranched systems are Newtonian fluids, and the viscosity and activation energy of their viscous flow depend substantially on the molecular parameters and regularity of the molecular structure.

Key words

hyperbranched polycarbosilanes dendrimers rheology 

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References

  1. 1.
    D. A. Tomalia, A. M. Naylor, W. A. Goddard, Angew. Chem., Int. Ed. Engl., 1990, 29, 138.CrossRefGoogle Scholar
  2. 2.
    D. A. Tomalia, H. D. Durst, Top. Curr. Chem., 1993, 165, 193.CrossRefGoogle Scholar
  3. 3.
    G. R. Newkome, C. N. Moorefield, F. Vogtle, Dendritic Macromolecules: Concepts, Syntheses, Perspectives, VCH, Weinheim, 1996.CrossRefGoogle Scholar
  4. 4.
    J. M. J. Frechet, D. A. Tomalia, Dendrimers and Other Dendritic Polymers, J. Wiley and Sons, West Sussex, 2001.CrossRefGoogle Scholar
  5. 5.
    D. A. Tomalia, Prog. Polym. Sci., 2005, 30, 294.CrossRefGoogle Scholar
  6. 6.
    I. Sendijarevic, A. J. McHugh, Macromolecules, 2000, 33, 590.CrossRefGoogle Scholar
  7. 7.
    S. Uppuluri, S. E. Keinath, D. A. Tomalia, P. R. Dvornic. Macromolecules, 1998, 31, 4498.CrossRefGoogle Scholar
  8. 8.
    A. P. Filippov, A. I. Amirova, E. V. Belyaeva, E. B. Tarabukina, N. A. Sheremetyeva, A. M. Muzafarov, Macromol. Symp., 2012, 316, 43.CrossRefGoogle Scholar
  9. 9.
    Z. Xu, J. S. Moore, Acta Polym., 1994, 45, 83.CrossRefGoogle Scholar
  10. 10.
    Y. N. Luponosov, S. A. Ponomarenko, N. M. Surin, O. V. Borshchev, E. A. Shumilkina, A. M. Muzafarov, Chem. Mater., 2009, 21, 447.CrossRefGoogle Scholar
  11. 11.
    R. M. Crooks, M. Zhao, L. Sun, V. Chechik, L. K. Yeung, Acc. Chem. Res., 2001, 34, 181.CrossRefGoogle Scholar
  12. 12.
    R. M. Crooks, B. I. Lemon, L. Sun, L. K. Yeung, M. Zhao, Top. Curr. Chem., 2001, 212, 81.CrossRefGoogle Scholar
  13. 13.
    E. R. Gillies, J. M. J. Frechet, Drug Discov. Today, 2005, 10, 35.CrossRefGoogle Scholar
  14. 14.
    L. Fogelstrom, E. Malmstrom, M. Johansson, A. Hult, ACS Appl. Mater. Interfaces, 2010, 2, 1679.CrossRefGoogle Scholar
  15. 15.
    L. Fogelstrom, E. Malmstrom, M. Johansson, A. Hult, Polym. Preprints, 2007, 48, 436.Google Scholar
  16. 16.
    M. N. Bochkarev, M. A. Katkova, Russ. Chem. Rev., 1995, 64, 1035.CrossRefGoogle Scholar
  17. 17.
    A. M. Muzafarov, O. B. Gorbatsevich, E. A. Rebrov, G. M. Ignatéva, T. B. Chenskaya, V. D. Myakushev, A. F. Bulkin, V. S. Papkov, Polym. Sci., 1993, 35, 1575.Google Scholar
  18. 18.
    J. Mathias, T. W. Carothers, J. Am. Chem. Soc., 1991, 113, 4043.CrossRefGoogle Scholar
  19. 19.
    L. C. Drohmann, M. Möller, O. B. Gorbatsevich, A. M. Muzafarov, J. Polym. Sci., Polym. Chem., 2000, 38, 741.CrossRefGoogle Scholar
  20. 20.
    G. M. Ignatéva, E. A. Rebrov, V. D. Myakushev, T. B. Chenskaya, Polym. Sci., Ser. A (Engl. Transl.), 1997, 39, 843 [Vysokomol. Soedin., Ser. A, 1997, 39, 1271].Google Scholar
  21. 21.
    V. V. Kazakova, V. D. Myakushev, T. V. Strelkova, A. M. Muzafarov, Polym. Sci., Ser. A (Engl. Transl.), 1999, 41, 283 [Vysokomol. Soedin., Ser. A, 1999, 41, 423].Google Scholar
  22. 22.
    C. Rissing, D. Y. Son, Organometallics, 2008, 27, 5394.CrossRefGoogle Scholar
  23. 23.
    A. N. Tarasenkov, E. V. Getmanova, M. I. Buzin, N. M. Surin, A. M. Muzafarov, Russ. Chem. Bull. (Int. Ed.), 2011, 60, 2544 [Izv. Akad. Nauk, Ser. Khim., 2011, 2495].CrossRefGoogle Scholar
  24. 24.
    E. B. Tarabukina, A. A. Shpyrkov, D. V. Potapova, E. V. Tarasova, N. A. Shumilkina, A. P. Filippov, A. M. Muzafarov, Polym. Sci., Ser. A (Engl. Transl.), 2005, 47, 1304 [Vysokomol. Soedin., Ser. A, 2005, 47, 1304].Google Scholar
  25. 25.
    E. B. Tarabukina, A. A. Shpyrkov, E. V. Tarasova, A. I. Amirova, A. P. Filippov, N. A. Sheremetyeva, A. M. Muzafarov, Polym. Sci., Ser. A (Engl. Transl.), 2009, 51, 150 [Vysokomol. Soedin., Ser. A, 2009, 51, 198].CrossRefGoogle Scholar
  26. 26.
    N. A. Sheremetyeva, N. V. Voronina, A. V. Bystrova, V. D. Miakushev, M. I. Buzin, A. M. Muzafarov, ACS book. Advances in Silicones and Silicone Modified Materials (ACS Symposium Series), Eds S. J. Clarson, M. J. Owen, S. D. Smith, M. E. Van Dyke, Washington, 2010, 10, 111.CrossRefGoogle Scholar
  27. 27.
    A. I. Amirova, E. V. Belyaeva, E. B. Tarabukina, N. A. Sheremetyeva, A. M. Muzafarov, A. P. Filippov, Polym. Sci., Ser. C (Engl. Transl.), 2010, 52, 70 [Vysokomol. Soedin., Ser. C, 2010, 52, 1304].CrossRefGoogle Scholar
  28. 28.
    A. I. Amirova, N. A. Sheremetyeva, A. P. Filippov, Int. J. Polym. Anal. Charact., 2013, 18, 339.CrossRefGoogle Scholar
  29. 29.
    E. B. Tarabukina, A. A. Shpyrkov, D. V. Potapova, A. P. Filippov, N. A. Shumilkina, A. M. Muzafarov, Polym. Sci., Ser. A (Engl. Transl.), 2006, 48, 974 [Vysokomol. Soedin., Ser. A, 2006, 48, 1655].CrossRefGoogle Scholar
  30. 30.
    E. A. Tatarinova, E. A. Rebrov, V. D. Myakushev, I. B. Meshkov, N. V. Demchenko, A. V. Bystrova, O. V. Lebedeva, A. M. Muzafarov, Russ. Chem. Bull. (Int. Ed.), 2004, 53, 2591 [Izv. Akad. Nauk, Ser. Khim., 2004, 11, 2484].CrossRefGoogle Scholar
  31. 31.
    A. P. Filippov, A. I. Amirova, T. Yu. Kirila, E. V. Belyaeva, N. A. Sheremetyeva, A. M. Muzafarov, Polym. Inter., 2015, 64, 780.CrossRefGoogle Scholar
  32. 32.
    A. Krupkova, J. Cermak, Z. Walterova, J. Horsky, Anal. Chem., 2007, 79, 1639.CrossRefGoogle Scholar
  33. 33.
    S. Uppuluri, F. A. Morrison, P. R. Dvornic, Macromolecules, 2000, 33, 2551.CrossRefGoogle Scholar
  34. 34.
    M. V. Mironova, A. V. Semakov, A. S. Tereshchenko, E. A. Tatarinova, E. V. Getmanova, A. M. Muzafarov, V. G. Kulichikhin, Vysokomol. Soedin., Ser. A, 2010, 52, 1960 [Polym. Sci., Ser. A (Engl. Transl.), 2010, 52].Google Scholar
  35. 35.
    G. V. Vinogradov, A. Ya. Malkin, Reologiya polimerov [Rheology of Polymers], Khimiya, Moscow, 1977, 440 pp. (in Russian).Google Scholar

Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • N. A. Sheremetyeva
    • 1
  • V. G. Vasiliev
    • 2
  • V. S. Papkov
    • 2
  • G. G. Pak
    • 3
  • V. D. Myakushev
    • 1
  • E. Yu. Kramarenko
    • 2
    • 4
    Email author
  • A. M. Muzafarov
    • 1
    • 2
  1. 1.N. S. Enikolopov Institute of Synthetic Polymeric MaterialsRussian Academy of SciencesMoscowRussian Federation
  2. 2.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation
  3. 3.M. V. Lomonosov Moscow State University of Fine Chemical TechnologiesMoscowRussian Federation
  4. 4.Faculty of PhysicsM. V. Lomonosov Moscow State UniversityMoscowRussian Federation

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