Russian Chemical Bulletin

, Volume 64, Issue 7, pp 1663–1670 | Cite as

Metal-containing systems based on chitosan and a collagen-chitosan composite

  • A. Yu. Vasil´kov
  • M. S. Rubina
  • A. V. Naumkin
  • Ya. V. Zubavichus
  • O. A. Belyakova
  • Yu. V. Maksimov
  • V. K. Imshennik
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Abstract

Metal-carrying polysaccharides based on chitosan and a collagen-chitosan composite (collachit) were obtained by modifying polymers by Au and Fe nanoparticles, which were prepared via metal vapor synthesis. Gold nanoparticles were synthesized using organosols with triethylamine; Fe nanoparticles, using the thermally labile bis(arene) complex, viz., bis(toluene)iron. The composition and structures of the resulting materials were studied by Mössbauer spectroscopy, XPS, and X-ray diagnostics using synchrotron radiation. Particles of Au (7.5–10 nm) and Fe (6–7 nm) were detected in metallopolymers by X-ray powder diffraction. The XPS analysis of gold-containing nanocomposites showed two states of Au4f. One of them is metallic with the binding energy of the Au4f7/2 peak equal to 83.8 eV, and another one is partially oxidized with the binding energy of the Au4f7/2 peak equal to 85.5 eV; the atomic concentrations of the two states are 16% and 84%, respectively. A comparative analysis of the Mössbauer spectra of iron-containing chitosan and collachit demonstrated that these two samples have similar structures. Thus, iron is present as a metallic phase (−30%) and a superparamagnetic gamma-iron oxide (−74%). The size of gamma-iron oxide nanoclusters in the samples can be estimated at −6–8 nm.

Key words

chitosan collagen-chitosan composite metal vapor synthesis nanoparticles gold iron XPS EXAFS/XANES Mössbauer spectroscopy 
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Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • A. Yu. Vasil´kov
    • 1
  • M. S. Rubina
    • 1
  • A. V. Naumkin
    • 1
  • Ya. V. Zubavichus
    • 2
  • O. A. Belyakova
    • 1
  • Yu. V. Maksimov
    • 3
  • V. K. Imshennik
    • 3
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation
  2. 2.National Research Centre “Kurchatov Institute”MoscowRussian Federation
  3. 3.N. N. Semenov Institute of Chemical PhysicsRussian Academy of SciencesMoscowRussian Federation

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