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Catalytic activity of Pd catalysts on different supports in hydrogenation of 1-phenylethenylphosphonic acid

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Abstract

Activity of palladium catalysts on different crystalline and amorphous supports was studied using hydrogenation of 1-phenylethenylphosphonic acid with molecular hydrogen as an example. Nanoscale Pd0 deposited on the surface of multi-wall carbon nanotubes (MWCNT) supported on microparticles of titanium oxide has proved the highest efficiency. The starting acid was quantitatively reduced for 1 h in the presence of this catalyst, 11 cycles of hydrogenation were carried out without loss of catalytic activity.

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Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    G. N. Bondarenko, O. G. Ganina & I. P. Beletskaya

  2. Academic Block-I, IIT Rajasthan, Indian Institute of Technology Rajsthan, Old Residency Road, Ratanada, Jodhpur, 342011, Rajasthan, India

    R. K. Sharma

Authors
  1. G. N. Bondarenko
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  2. O. G. Ganina
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  3. R. K. Sharma
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  4. I. P. Beletskaya
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Correspondence to G. N. Bondarenko.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1856–1859, August, 2014.

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Bondarenko, G.N., Ganina, O.G., Sharma, R.K. et al. Catalytic activity of Pd catalysts on different supports in hydrogenation of 1-phenylethenylphosphonic acid. Russ Chem Bull 63, 1856–1859 (2014). https://doi.org/10.1007/s11172-014-0676-6

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  • DOI: https://doi.org/10.1007/s11172-014-0676-6

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