Advertisement

Russian Chemical Bulletin

, Volume 63, Issue 8, pp 1647–1655 | Cite as

Simulation of chemical properties of superheavy elements from the island of stability

  • Yu. A. Demidov
  • A. V. Zaitsevskii
Reviews

Abstract

The review covers main methods of the first-principle based electronic structure simulation used for the prediction of the properties of superheavy element atoms and compounds. The areas of applicability of these methods and the principal and practical limitations of their accuracy are analyzed. The regularities in the changes of the chemical properties on going from superheavy elements to their closest homologs are discussed.

Key words

simulation of chemical properties superheavy elements electronic structure 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Yu. Ts. Oganessian, S. N. Dmitriev, Russ. Chem. Rev., 2009, 78, 1165.CrossRefGoogle Scholar
  2. 2.
    Yu. Oganessian, Eur. Phys. J. A, 2009, 42, 361.CrossRefGoogle Scholar
  3. 3.
    Yu. Ts. Oganessian, F. Sh. Abdullin, P. D. Bailey, D. E. Benker, M. E. Bennett, S. N. Dmitriev, J. G. Ezold, J. H. Hamilton, R. A. Henderson, M. G. Itkis, Yu. V. Lobanov, A. N. Mezentsev, K. J. Moody, S. L. Nelson, A. N. Polyakov, C. E. Porter, A. V. Ramayya, F. D. Riley, J. B. Roberto, M. A. Ryabinin, K. P. Rykaczewski, R. N. Sagaidak, D. A. Shaughnessy, I. V. Shirokovsky, M. A. Stoyer, V. G. Subbotin, R. Sudowe, A. M. Sukhov, Yu. S. Tsyganov, V. K. Utyonkov, A. A. Voinov, G. K. Vostokin, P. A. Wilk, Phys. Rev. Lett., 2010, 104, 142502.CrossRefGoogle Scholar
  4. 4.
    Yu. Oganessian, J. Phys. Conf. Ser., 2011, 312, 082003.CrossRefGoogle Scholar
  5. 5.
    S. G. Nilsson, S. G. Thompson, C. F. Tsang, Phys. Lett. B, 1969, 28, 458.CrossRefGoogle Scholar
  6. 6.
    A. Sobiczewski, K. Pomorski, Progr. Particle Nucl. Phys., 2007, 58, 292.CrossRefGoogle Scholar
  7. 7.
    R. Eichler, J. Phys.: Conf. Ser., 2013, 420, 012003.Google Scholar
  8. 8.
    J. Meng, H. Toki, S. G. Zhou, S. Q. Zhang, W. H. Long, L. S. Geng, Progr. Particle Nucl. Phys., 2006, 57, 470.CrossRefGoogle Scholar
  9. 9.
    K. Rutz, M. Bender, T. Bürvenich, T. Schilling, P.-G. Reinhard, J. A. Maruhn, W. Greiner, Phys. Rev. C, 1997, 56, 238.CrossRefGoogle Scholar
  10. 10.
    Y. T. Oganessian, V. K. Utyonkov, Y. V. Lobanov, F. S. Abdullin, A. N. Polyakov, R. N. Sagaidak, I. V. Shirokovsky, Y. S. Tsyganov, A. A. Voinov, A. N. Mezentsev, V. G. Subbotin, A. M. Sukhov, K. Subotic, V. I. Zagrebaev, S. N. Dmitriev, Phys. Rev. C, 2009, 79, 024603.CrossRefGoogle Scholar
  11. 11.
    D. C. Hoffman, J. Radioanal. Nucl. Chem., 2008, 276, 525.CrossRefGoogle Scholar
  12. 12.
    I. Zvara, Experimental Developments in Gas-Phase Radiochemistry, Springer, Netherlands, 2008, 225 pp.Google Scholar
  13. 13.
    R. Eichler, N. V. Aksenov, A. V. Belozerov, G. A. Bozhikov, V. I. Chepigin, S. N. Dmitriev, R. Dressler, H. W. Gaeggeler, V. A. Gorshkov, F. Haenssler, M. G. Itkis, A. Laube, V. Ya. Lebedev, O. N. Malyshev, Yu. Ts. Oganessian, O. V. Petrushkin, D. Piguet, P. Rasmussen, S. V. Shishkin, A. V. Shutov, A. I. Svirikhin, E. E. Tereshatov, G. K. Vostokin, M. Wegrzecki, A. V. Yeremin, Nature, 2007, 447, 72.CrossRefGoogle Scholar
  14. 14.
    R. Eichler, N. V. Aksenov, Y. V. Albin, A. V. Belozerov, G. A. Bozhikov, V. I. Chepigin, S. N. Dmitriev, R. Dressler, H. W. Gaeggeler, V. A. Gorshkov, G. S. Henderson, Radiochim. Acta, 2010, 98, 133.CrossRefGoogle Scholar
  15. 15.
    H. W Gäggeler, Russ. Chem. Rev., 2009, 78, 1139.CrossRefGoogle Scholar
  16. 16.
    V. Pershina, J. Anton, T. Jacob, J. Chem. Phys., 2009, 131, 084713.CrossRefGoogle Scholar
  17. 17.
    V. Pershina, A. Borschevsky, J. Anton, J. Chem. Phys., 2012, 136, 134317.CrossRefGoogle Scholar
  18. 18.
    A. V. Zaitsevskii, E. A. Rykova, A. V. Titov, Russ. Chem. Rev., 2008, 77, 205.CrossRefGoogle Scholar
  19. 19.
    V. Pershina, Russ. Chem. Rev., 2009, 78, 1243.CrossRefGoogle Scholar
  20. 20.
    A. Türler, V. Pershina, Chem. Rev., 2013, 113, 1237.CrossRefGoogle Scholar
  21. 21.
    A. Zaitsevskii, E. Rykova, N. S. Mosyagin, A. V. Titov, Centr. Eur. J. Phys., 2006, 4, 448.CrossRefGoogle Scholar
  22. 22.
    A. N. Petrov, N. S. Mosyagin, A. V. Titov, Yadernaya Fiz., 2009, 72, 429 [Phys. Atom. Nucl. (Engl. Transl.), 2009, 72].Google Scholar
  23. 23.
    W. H. E. Schwarz, E. M. van Wezenbeek, E. J. Baerends, J. G. Snijders, J. Phys. B: Atom., Mol. Optical Phys., 1989, 22, 1515.CrossRefGoogle Scholar
  24. 24.
    N. S. Mosyagin, A. N. Petrov, A. V. Titov, I. I. Tupitsyn, Recent Advances in the Theory of Chemical and Physical Systems, Eds J. P. Julien, J. Maruani, D. Mayou, S. Wilson, G. Delgado-Barrio, Springer, Netherlands, 2006, 229.Google Scholar
  25. 25.
    J. Sucher, Phys. Rev. A, 1980, 22, 348.CrossRefGoogle Scholar
  26. 26.
    G. E. Brown, D. G. Ravenhall, Proc. Royal Soc. London, Ser. A: Math. Phys. Sci., 1951, 552.Google Scholar
  27. 27.
    A. V. Titov, N. S. Mosyagin, T. A. Isaev, A. N. Petrov, Phys. Atom. Nucl., 2003, 66, 1152.CrossRefGoogle Scholar
  28. 28.
    A. Borschevsky, V. Pershina, E. Eliav, U. Kaldor, Phys. Rev. A, 2010, 82, 062503.CrossRefGoogle Scholar
  29. 29.
    A. V. Titov, N. S. Mosyagin, T. A. Isaev, A. N. Petrov, Phys. Rev. A, 2013, 87, 022502.CrossRefGoogle Scholar
  30. 30.
    E. Eliav, U. Kaldor, in Relativistic Methods for Chemists, Eds M. Barysz, Ya. Ishikawa, Springer, Netherlands, 2010, 279.Google Scholar
  31. 31.
    T. Nakajima, K. Hirao, Chem. Phys. Lett., 2000, 329, 511.CrossRefGoogle Scholar
  32. 32.
    M. Seth, P. Schwerdtfeger, M. Dolg, K. Færi, B. A. Hess, U. Kaldor, Chem. Phys. Lett., 1996, 250, 461.CrossRefGoogle Scholar
  33. 33.
    M. Seth, P. Schwerdtfeger, K. Færi, J. Chem. Phys., 1999, 111, 6422.CrossRefGoogle Scholar
  34. 34.
    A. V. Titov, N. S. Mosyagin, Inter. J. Quant. Chem., 1999, 71, 359.CrossRefGoogle Scholar
  35. 35.
    N. S. Mosyagin, A. Zaitsevskii, A. V. Titov, Int. Rev. At. Mol. Phys., 2010, 1, 63.Google Scholar
  36. 36.
    T. Hangele, M. Dolg, M. Hanrath, X. Cao, P. Schwerdtfeger, J. Chem. Phys., 2012, 136, 214105.CrossRefGoogle Scholar
  37. 37.
    T. Hangele, M. Dolg, P. Schwerdtfeger, J. Chem. Phys., 2013, 138, 174113.CrossRefGoogle Scholar
  38. 38.
    M. Dolg, Theoret. Comput. Chem., 2002, 11, 793.CrossRefGoogle Scholar
  39. 39.
    R. B. Ross, J. M. Powers, T. Atashroo, W. C. Ermler, L. A. LaJohn, P. A. Christiansen, J. Chem. Phys., 1990, 93, 6654.CrossRefGoogle Scholar
  40. 40.
    C. S. Nash, B. E. Bursten, J. Chem. Phys. A, 1999, 103, 402.CrossRefGoogle Scholar
  41. 41.
    V. A. Dzuba, V. V. Flambaum, M. G. Kozlov, Phys. Rev. A, 1996, 54, 3948.CrossRefGoogle Scholar
  42. 42.
    E. Eliav, M. J. Vilkas, Ya. Ishikawa, U. Kaldor, J. Chem. Phys., 2005, 122, 224113.CrossRefGoogle Scholar
  43. 43.
    V. A. Dzuba, Phys. Rev. A, 2013, 88, 042516.CrossRefGoogle Scholar
  44. 44.
    T. H. Dinh, V. A. Dzuba, V. V. Flambaum, J. S. M. Ginges, Phys. Rev. A, 2008, 78, 054501.CrossRefGoogle Scholar
  45. 45.
    N. S. Mosyagin, T. A. Isaev, A. V. Titov, J. Chem. Phys., 2006, 124, 224302.CrossRefGoogle Scholar
  46. 46.
    L. V. Skripnikov, N. S. Mosyagin, A. V. Titov, Chem. Phys. Lett., 2012, 555, 79.CrossRefGoogle Scholar
  47. 47.
    M. V. Ramana, A. K. Rajagopal, J. Phys. C: Solid State Phys., 1981, 14, 4291.CrossRefGoogle Scholar
  48. 48.
    A. H. MacDonald, S. H. Vosko, J. Phys. C: Solid State Phys., 1979, 12, 2977.CrossRefGoogle Scholar
  49. 49.
    A. K. Rajagopal, J. Callaway, Phys. Rev. B, 1973, 7, 1912.CrossRefGoogle Scholar
  50. 50.
    A. Zaitsevskii, C. van Wüllen, E. A. Rykova, A. V. Titov, Phys. Chem. Chem. Phys., 2010, 12, 4152.CrossRefGoogle Scholar
  51. 51.
    A. Zaitsevskii, A. V. Titov, Inter. J. Quant. Chem., 2013, 113, 1772.CrossRefGoogle Scholar
  52. 52.
    W. Kohn, Y. Meir, D. E. Makarov, Phys. Rev. Lett., 1998, 80, 4153.CrossRefGoogle Scholar
  53. 53.
    O. D. Häberlen, S.-C. Chung, M. Stener, N. Rösch, J. Chem. Phys., 1997, 106, 5189.CrossRefGoogle Scholar
  54. 54.
    A. Zaitsevskii, C. van Wüllen, A. V. Titov, J. Chem. Phys., 2010, 132, 081102.CrossRefGoogle Scholar
  55. 55.
    A. Zaitsevskii, A. V. Titov, A. A. Rusakov, C. van Wüllen, Chem. Phys. Lett., 2011, 508, 329.CrossRefGoogle Scholar
  56. 56.
    E. Eliav, U. Kaldor, Ya. Ishikawa, Phys. Rev. A, 1995, 52, 2765.CrossRefGoogle Scholar
  57. 57.
    R. Eichler, N. V. Aksenov, A. V. Belozerov, G. A. Bozhikov, V. I. Chepigin, S. N. Dmitriev, R. Dressler, H. W. Gäggeler, A. V. Gorshkov, M. G. Itkis, Angew. Chem., Int. Ed., 2008, 47, 3262.CrossRefGoogle Scholar
  58. 58.
    E. A. Rykova, A. Zaitsevskii, N. S. Mosyagin, T. A. Isaev, A. V. Titov, J. Chem. Phys., 2006, 125, 241102.CrossRefGoogle Scholar
  59. 59.
    A. V. Zaitsevskii, C. van Wüllen, A. V. Titov, Russ. Chem. Rev., 2009, 78, 1173.CrossRefGoogle Scholar
  60. 60.
    A. Landau, E. Eliav, Ya. Ishikawa, U. Kaldor, J. Chem. Phys., 2001, 114, 2977.CrossRefGoogle Scholar
  61. 61.
    Yu. A. Demidov, A. V. Zaitsevskii, Radiokhimiya, 2013, 55, 385 [Russ. Radiochem. (Engl. Transl.), 2013, 55].Google Scholar
  62. 62.
    Yu. A. Demidov, A. Zaitsevskii, R. Eichler, Phys. Chem. Chem. Phys., 2014, 16, 2268.CrossRefGoogle Scholar
  63. 63.
    A. N. Petrov, N. S. Mosyagin, A. V. Titov, A. V. Zaitsevskii, E. A. Rykova, Phys. Atom. Nucl., 2009, 72, 396.CrossRefGoogle Scholar
  64. 64.
    M. Seth, P. Schwerdtfeger, M. Dolg, J. Chem. Phys., 1997, 106, 3623.CrossRefGoogle Scholar
  65. 65.
    X. Wang, L. Andrews, S. Riedel, M. Kaupp, Angew. Chem., Int. Ed., 2007, 46, 8371.CrossRefGoogle Scholar
  66. 66.
    B. S. Fox-Beyer, C. van Wüllen, Chem. Phys., 2012, 395, 95.CrossRefGoogle Scholar
  67. 67.
    A. Serov, R. Eichler, R. Dressler, D. Piguet, A. Türler, A. Vögele, D. Wittwer, H. W. Gäggeler, Radiochimica Acta, 2013, 101, 421.CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  1. 1.B. P. Konstantinov Petersburg Nuclear Physics InstituteGatchina, Leningrad RegionRussian Federation
  2. 2.National Research Centre “Kurchatov Institute”MoscowRussian Federation

Personalised recommendations