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New methods of heterogeneous catalysis for lignocellulosic biomass conversion to chemicals

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Abstract

This review deals with the use of solid catalysts for the enhancement of the efficiency and the development of a new generation of environmentally friendly, energy and resource efficient processes for the deep processing of lignocellulosic biomass to desired chemicals. The oxidative delignification of wood with hydrogen peroxide in the presence of the suspended TiO2 catalyst, the oxidation of wood with molecular oxygen in the presence of copper catalysts, the acidcatalyzed conversion of cellulose to glucose and levulinic acid, and the thermal conversion of lignin to fuel additives on solid acid catalysts are analyzed. New integrated processes based on the heterogeneous catalytic oxidation are suitable for the complex processing of lignocellulosic biomass to produce valuable chemicals and engine fuel components without the use of toxic and corrosion-active reagents.

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Author information

Correspondence to B. N. Kuznetsov.

Additional information

According to the materials of the International Conference “Current Problems of Chemical Physics” (October 9–12, 2012, Yerevan, Republic of Armenia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1493–1503, July, 2013.

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Kuznetsov, B.N., Chesnokov, N.V., Yatsenkova, O.V. et al. New methods of heterogeneous catalysis for lignocellulosic biomass conversion to chemicals. Russ Chem Bull 62, 1493–1502 (2013). https://doi.org/10.1007/s11172-013-0213-z

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Key words

  • lignocellulosic biomass
  • oxidative and acid-catalyzed conversions
  • solid catalysts
  • cellulose
  • glucose
  • levulinic acid
  • fuel additives