Russian Chemical Bulletin

, Volume 62, Issue 3, pp 705–709 | Cite as

Synthesis of diethoxy(phenyl)silane and its polycondensation in acetic acid

  • S. A. MileninEmail author
  • A. A. Kalinina
  • N. V. Demchenko
  • N. G. Vasilenko
  • A. M. Muzafarov
Full Articles


Low-temperature reaction between phenylmagnesium chloride and triethoxysilane at lowered affords diethoxy(phenyl)silane, whose polycondensation in acetic acid gives oligomeric (phenyl)hydrosiloxanes.

Key words

silanes hydrosilanes hydrosiloxane oligomers polycondensation 


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  1. 1.
    Z. V. Belyakova, E. A. Komarov, V. Zh. Bykovchenko, O. L. Ershov, E. A. Chernyashev, P. A. Storozhenko, Zh. Obshch. Khim., 2009, 79, 1292 [Russ. J. Gen. Chem. (Engl. Transl.), 2009, 79, 1650].Google Scholar
  2. 2.
    A. D. Petrov, V. A. Ponomarenko, G. V. Odabashyan, Dokl. Akad. Nauk SSSR, 1959, 126, 1009 [Dokl. Chem. (Engl. Transl.), 1959].Google Scholar
  3. 3.
    O. Minge, N. W. Mitzel, H. Schmidbaur, Organometallics, 2002, 21, 680.CrossRefGoogle Scholar
  4. 4.
    Kai Su, J. V. DeGroot, Jr., A. W. Norris, P. Y. Lo, Proc. SPIE, 2006, 60291C.Google Scholar
  5. 5.
    Y. Gunji, Y. Yamashita, T. Ikeno, T. Yamada, Chem. Lett., 2006, 35, 714.CrossRefGoogle Scholar
  6. 6.
    J. Ohshita, R. Taketsugu, Y. Nakahara, A. Kunai, J. Organomet. Chem., 2004, 689, 3258.CrossRefGoogle Scholar
  7. 7.
    E. V. Egorova, N. G. Vasilenko, N. V. Demchenko, E. A. Tatarinova, A. M. Muzafarov, Dokl. Akad. Nauk, 2009, 424, 200 [Dokl. Chem. (Engl. Transl.), 2009, 424, 15].Google Scholar
  8. 8.
    A. A. Bychkova, F. V. Soskov, A. I. Demchenko, P. A. Storozhenko, A. M. Muzafarov, Russ. Chem. Bull. (Int. Ed.), 2011, 60, 2384 [Izv. Akad. Nauk, Ser. Khim., 2011, 2337].CrossRefGoogle Scholar
  9. 9.
    L. F. Armaredo, D. D. Perkin, Purification of laboratory Chemicals, Butterworth Heinemann, Oxford, 2002, p. 530.Google Scholar

Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  • S. A. Milenin
    • 1
    Email author
  • A. A. Kalinina
    • 1
  • N. V. Demchenko
    • 1
  • N. G. Vasilenko
    • 1
  • A. M. Muzafarov
    • 1
  1. 1.N. S. Enikolopov Institute of Synthetic Polymer MaterialsRussian Academy of SciencesMoscowRussian Federation

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