Russian Chemical Bulletin

, Volume 62, Issue 3, pp 672–677 | Cite as

Structure determination of bis{(4Z)-1-(2-azidoethyl)-4-[(pyridin-2-yl)methylidene]-2-thiolatoimidazol-5(4H)-one}dicopper chloride from X-ray powder diffraction data

  • A. V. Mironov
  • E. V. Antipov
  • E. K. Beloglazkina
  • A. G. Majouga
  • O. O. Krasnovskaya
  • V. M. Gerasimov
  • N. V. Zyk
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Abstract

The new tridentate organic N2S-type ligand, (4Z)-1-(2-azidoethyl)-4-[(pyridin-2-yl)-methylidene]-2-thioxoimidazol-5(4H)-one (LH), was synthesized. The reaction of LH with copper(II) chloride in a CH2Cl2/MeOH mixture afforded the coordination compound of the composition L2Cu2Cl (3). The crystal structure of 3 was solved and refined from X-ray powder diffraction data. Complex 3 has a binuclear structure with a short interatomic Cu-Cu distance and one bridging chlorine atom, which is located almost symmetrically with respect to both metal atoms. The planar organic ligands are noncoplanar and are at an angle of 53.56(1)° to each other.

Key words

imidazoles copper complex structure 
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Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  • A. V. Mironov
    • 1
  • E. V. Antipov
    • 1
  • E. K. Beloglazkina
    • 1
  • A. G. Majouga
    • 1
  • O. O. Krasnovskaya
    • 1
  • V. M. Gerasimov
    • 1
  • N. V. Zyk
    • 1
  1. 1.Department of ChemistryM. V. Lomonosov Moscow State UniversityMoscowRussian Federation

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