Russian Chemical Bulletin

, Volume 61, Issue 6, pp 1255–1256 | Cite as

2-Methyl-4,5-dihydrofurane hydroformylation

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Abstract

The synthesis of 2-methyl-3-formyl tetrahydrofurane as E-isomer via the hydroformylation of 2-methyl-4,5-dihydrofurane in the presence of complex phosphine-containing Rh-catalysts is performed. The dependence of the catalytic system type, pressure and temperature on the 2-methyl-4,5-dihydrofurane conversion and the selectivity of the formation of the aldehyde obtained is investigated.

Key words

2-methyl-4,5-dihydrofurane hydroformylation complex phosphine-containing Rh-catalysts 2-methyl-3-formyl tetrahydrofurane 
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Literature

  1. 1.
    H. Frauenrath, J. Runsink, J. Org. Chem., 1987, 52, 2707.CrossRefGoogle Scholar
  2. 2.
    H.-D. Scharf, H. Frauenrath, Chem. Ber., 1980, 113, 1472.CrossRefGoogle Scholar
  3. 3.
    H. Frauenrath, J. Runsink, H.-D. Scharf, Chem. Ber., 1982, 115, 2728.CrossRefGoogle Scholar
  4. 4.
    H. Suzuki, H. Yashima, T. Hirose, M. Takahashi, Y. MoroOka, T. Ikawa, Tetrahedron Lett., 1980, 21, 4927.CrossRefGoogle Scholar
  5. 5.
    E. Yu. Vol’f, T. Yu. Solov’eva, M. M. Vartanyan, L. Yu. Brezhnev, A. L. Lapidus, Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.), 1989, 38, 2356CrossRefGoogle Scholar
  6. 6.
    G. Henrici-Olive, S. Olive, Coordination and Catalysis, Verlag Chemi, Weinheim—New York, 1977; N. Kuznik, S. Krompiec, Coord. Chem. Rev., 2007, 251, 222; N. Ruiz, A. Polo, S. Castillón, C. Claver, J. Mol. Catal. A: Chem., 1999, 137, 93.Google Scholar
  7. 7.
    US Pat. 4376208; Chem. Abstrs, 1983, 98, 215473.Google Scholar
  8. 8.
    A. Polo, J. Real, C. Claver, S. Castillón, J. C. Bayón, J. Chem. Soc., Chem. Commun., 1990, 600.Google Scholar
  9. 9.
    A. Polo, C. Claver, S. Castillón, A. Ruiz, J. C. Bayón, J. Real, C. Mealli, D. Masi, Organometallics, 1992, 11, 3525.CrossRefGoogle Scholar
  10. 10.
    M. Diéguez, O. Pamies, C. Claver, Chem. Commun., 2005, 1221.Google Scholar
  11. 11.
    S. H. Chikkali, R. Bellini, G. Berthon-Gelloz, J. I. van der Vlugt, B. de Bruin, J. N. H. Reek, Chem. Commun., 2010, 46, 1244.CrossRefGoogle Scholar
  12. 12.
    A. Gual, C. Godard, S. Castillón, C. Claver, Adv. Synth. Catal., 2010, 463.Google Scholar
  13. 13.
    J. Falbe, F. Korte, Chem. Ber., 1964, 97, 1104.CrossRefGoogle Scholar
  14. 14.
    Handbuch der Präparativen Anorganischen Chimie in drei Bänden Dritter Band, Ed. G. Brauer, Ferdinand Enke Verlag, Stuttgart, 1981.Google Scholar

Copyright information

© Springer Science+Business Media New York 2012

Authors and Affiliations

  • E. Yu. Vol’f
    • 1
  • M. M. Vartanya
    • 1
  • A. L. Lapidus
    • 1
  1. 1.N. D. Zelinsky Institute of Organic Chemistry of Russian Academy of SciencesMoscowRussian Federation

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