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Russian Chemical Bulletin

, Volume 61, Issue 1, pp 148–157 | Cite as

Synthesis of crown-containing and related hetarylphenylacetylenes and acetylenyl dyes

  • A. I. Vedernikov
  • N. A. Lobova
  • L. G. Kuz’mina
  • N. A. Aleksandrova
  • S. K. Sazonov
  • J. A. K. Howard
  • S. P. Gromov
Article

Abstract

New 15(18)-crown-5(6)-containing and model methoxy-substituted 1-hetaryl-2-phenylacetylenes of the 4-pyridine and 2-benzothiazole series were synthesized using the addition of bromine to the ethylene fragment of the corresponding styrylheterocycles followed by dehydrobromination under the action of potassium tert-butoxide. The quaternization of the pyridylphenylacetylenes afforded new acetylenyl dyes. The structures of five synthesized compounds were determined by X-ray diffraction analysis.

Key words

styrylheterocycles hetarylphenylacetylenes crown ethers synthesis structure X-ray diffraction analysis 

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Copyright information

© Springer Science+Business Media New York 2012

Authors and Affiliations

  • A. I. Vedernikov
    • 1
  • N. A. Lobova
    • 1
  • L. G. Kuz’mina
    • 2
  • N. A. Aleksandrova
    • 1
  • S. K. Sazonov
    • 1
  • J. A. K. Howard
    • 3
  • S. P. Gromov
    • 1
  1. 1.Photochemistry CentreRussian Academy of SciencesMoscowRussian Federation
  2. 2.N. S. Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussian Federation
  3. 3.Chemistry DepartmentDurham UniversityDurhamUK

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