Russian Chemical Bulletin

, Volume 60, Issue 8, pp 1647–1650 | Cite as

Synthesis of bimetallic cage-like metalloorganosiloxanes from polymeric metallosiloxanes

  • B. G. Zavin
  • N. V. Sergienko
  • N. V. Cherkun
  • A. N. Bilyachenko
  • O. M. Starikova
  • A. A. Korlyukov
  • M. S. Dronova
  • M. M. Levitskii
  • G. I. Timofeeva
Full Articles
First Online:
Received:
Accepted:

Abtract

A new approach to the synthesis of the cage-like metalloorganosiloxanes (MOS) was developed. Unlike existing schemes for the synthesis of the cage-like MOS from monomeric structural units, regular polyhedral structures were formed from irregular polymeric MOS by their reaction with sodium phenylsilanolate. Efficiency of the method suggested was confirmed by directed synthesis of the earlier described bimetallic cage-like (CuII,Na)- and (FeIII,Na)-phenylsiloxanes in 69 and 47% yields, respectively. Compounds that obtained were identified by destructive trimethylsilylation, GPC, 1H NMR, and X-ray crystallography.

Key words

cage-like and polymeric metalloorganosiloxanes bimetallic metallosiloxanes (copper,sodium)phenylsiloxane (iron,sodium)phenylsiloxane sodium phenylsilanolate 
This is a preview of subscription content, log in to check access.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    M. M. Levitskii, B. G. Zavin, A. N. Bilyachenko, Usp. Khim., 2007, 76, 907 [Russ. Chem. Bull. (Engl. Transl.), 2007, 76].Google Scholar
  2. 2.
    M. G. Voronkov, V. P. Mileshkevich, Yu. A. Yuzhelevskii, Siloksanovaya svyaz’ [Siloxane Bond], Nauka, Novosibirsk, 1976 (in Russian).Google Scholar
  3. 3.
    M. G. Voronkov, E. A. Maletina, V. K. Roman, Geterosiloxany [Heterosiloxanes], Nauka, Novosibirsk, 1984 (in Russian).Google Scholar
  4. 4.
    A. A. Zhdanov, N. V. Sergienko, E. S. Trankina, Russ. Khim. Zh., 2001, 45, 44 [Mendeleev Chem. J. (Engl. Transl.), 2001, 45].Google Scholar
  5. 5.
    M. M. Levitskii, S. P. Knyazev, A. N. Bilyachenko, B. G. Zavin, Tez. dokl. XX simpoziuma “Sovremennaya khimicheskaya fizika” [Abstracts of the XX Symposium “Modern Chemical Physics”] (September 15–26, 2008, Burevestnik MSU Guest house, Tuapse), p. 11 (in Russian).Google Scholar
  6. 6.
    A. A. Zhdanov, N. V. Sergienko, E. S. Trankina, Izv. Akad. Nauk, Ser. Khim., 1998, 2530 [Russ. Chem. Bull. (Engl. Transl.), 1998, 2448].Google Scholar
  7. 7.
    I. L. Dubchak, V. E. Shklover, A. A. Zhdanov, Yu. T. Struchkov, Zh. Strukt. Khim, 1980, 21, 103 [J. Struct. Chem. USSR (Engl. Transl.), 1980, 21].Google Scholar
  8. 8.
    V. A. Igonin, S. V. Lindeman, Yu. T. Struchkov, O. I. Shchegolikhina, A. A. Zhdanov, Yu. A. Molodtsova, I. V. Razumovskaya, Metalloorg. Khim, 1991, 4, 1355 [Organomet. Chem. USSR (Engl. Transl.), 1991, 4].Google Scholar
  9. 9.
    A. N. Bilyachenko, A. A. Korlyukov, M. M. Levitskii, M. Yu. Antipin, B. G. Zavin, Izv. Akad. Nauk, Ser. Khim., 2007, 522 [Russ. Chem. Bull., Int. Ed., 2007, 46].Google Scholar
  10. 10.
    B. G. Zavin, N. V. Sergienko, E. V. Gorodnichev, V. D. Myakushev, A. A. Korlyukov, M. Yu. Antipin, Mendeleev Commun., 2005, 15, 245.CrossRefGoogle Scholar
  11. 11.
    A. A. Zhdanov, O. I. Shchegolikhina, Yu. A. Molodtsova, T. V. Strelkova. Dokl. Akad. Nauk, 1992, 325, 1186.Google Scholar
  12. 12.
    M. M. Levitskii, A. I. Kokorin, V. V. Smirnov, N. V. Karpilovskaya, A. V. Kudryashov, S. M. Nevskaya, E. N. Golubeva, Izv. Akad. Nauk, Ser. Khim., 1998, 1946 [Russ. Chem. Bull. (Engl. Transl.), 1998, 47, 1892].Google Scholar
  13. 13.
    A. A. Zhdanov, K. A. Andrianov, M. M. Levitskii, Vysokomolekulyar. Soedin., 1976, 18, A, 2264 [Polym. Sci. USSR (Engl. Transl.), 1976, 18A].Google Scholar

Copyright information

© Springer-Verlag 2011

Authors and Affiliations

  • B. G. Zavin
    • 1
  • N. V. Sergienko
    • 1
  • N. V. Cherkun
    • 1
  • A. N. Bilyachenko
    • 1
  • O. M. Starikova
    • 1
  • A. A. Korlyukov
    • 1
  • M. S. Dronova
    • 1
  • M. M. Levitskii
    • 1
  • G. I. Timofeeva
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

Personalised recommendations