Russian Chemical Bulletin

, Volume 58, Issue 11, pp 2250–2257

Synthesis and structure of novel chiral amido-imine complexes of aluminum, gallium, and indium

  • A. N. Tishkina
  • A. N. Lukoyanov
  • A. G. Morozov
  • G. K. Fukin
  • K. A. Lyssenko
  • I. L. Fedushkin
Full Articles

Abstract

The reactions of 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (dpp-BIAN, 1) with tri-iso-butylaluminum, triethylgallium or trimethylindium give the novel amido-imine complexes (Bui—dpp-BIAN)AlBui2 (4), (Et—dpp-BIAN)GaEt2 (5), and (Me—dpp-BIAN)InMe2 (6), respectively. The reaction of (dpp-BIAN)AlI(Et2O) (7) with allyl bromide affords analogous chiral amido-imine derivative (All—dpp-BIAN)AlBrI (8). Hydrolysis of 8 affords the amino-imino compound (All—dpp-BIAN)H (9). The new compounds 46, 8, and 9 have been characterized by 1H NMR and IR spectroscopy. The molecular structures of 5, 6, and 9 were determined by single crystal X-ray analysis.

Key words

aluminum gallium indium diimines chiral ligands X-ray diffraction analysis. 

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Copyright information

© Springer Science+Business Media, Inc.  2009

Authors and Affiliations

  • A. N. Tishkina
    • 1
  • A. N. Lukoyanov
    • 1
  • A. G. Morozov
    • 1
  • G. K. Fukin
    • 1
  • K. A. Lyssenko
    • 2
  • I. L. Fedushkin
    • 1
  1. 1.A. G. Razuvaev Institute of Organometallic ChemistryRussian Academy of SciencesNizhnii NovgorodRussian Federation
  2. 2.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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