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Russian Chemical Bulletin

, Volume 58, Issue 5, pp 968–970 | Cite as

Synthesis of metallacarborane triple-decker complexes with the bridging diborolyl ligand

  • D. V. Muratov
  • A. S. Romanov
  • P. V. Petrovskii
  • Z. A. Starikova
  • A. R. KudinovEmail author
Full Articles

Abstract

Triple-decker complexes CpCo(μ-1,3-C3B2Me5)M(η-7,8-C2B9H11) (M = Rh (3), Ir (4)) were synthesized by the reaction of [CpCo(μ-1,3-C3B2Me5)MBr2]2 (M = Rh, Ir) with Tl[TlC2B9H11]. The structure of 3 was established by X-ray diffraction analysis.

Key words

boron-containing heterocycles iridium cobalt rhodium sandwich compounds triple-decker complexes 

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Copyright information

© Springer Science+Business Media, Inc.  2009

Authors and Affiliations

  • D. V. Muratov
    • 1
  • A. S. Romanov
    • 1
  • P. V. Petrovskii
    • 1
  • Z. A. Starikova
    • 1
  • A. R. Kudinov
    • 1
    Email author
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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