Russian Chemical Bulletin

, 57:2307 | Cite as

Phosphorus derivatives of carboranes as ligands for Pd-catalyzed cross-coupling reactions

  • A. A. Tyutyunov
  • S. E. Lyubimov
  • E. G. Rys
  • T. A. Verbitskaya
  • P. V. Petrovskii
  • V. A. Davankov
  • V. N. Kalinin
Full Articles

Abstract

Carborane-containing phosphine ligands having different steric and electronic properties were synthesized. Testing of these ligands in the Pd-catalyzed Suzuki—Miyaura reaction showed higher catalytic activity for sterically congested phosphine ligands with acceptor carborane substituents.

Key words

carboranes cross-coupling phenylboronic acid aryl halides phosphines phosphites 

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Copyright information

© Springer Science+Business Media, Inc.  2008

Authors and Affiliations

  • A. A. Tyutyunov
    • 1
  • S. E. Lyubimov
    • 1
  • E. G. Rys
    • 1
  • T. A. Verbitskaya
    • 1
  • P. V. Petrovskii
    • 1
  • V. A. Davankov
    • 1
  • V. N. Kalinin
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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