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Russian Chemical Bulletin

, Volume 57, Issue 4, pp 793–801 | Cite as

Unusual supramolecular donor—acceptor complexes of bis(crown)stilbenes and bis(crown)azobenzene with viologen analogs

  • S. P. Gromov
  • A. I. Vedernikov
  • E. N. Ushakov
  • M. V. Alfimov
Reviews

Abstract

The results of the comprehensive study of novel supramolecular donor-acceptor complexes of bis(crown)stilbenes and bis(crown)azobenzene with viologen analogs are generalized. The original methodology for self-assembling of the organic donor-acceptor complexes possessing a very high thermodynamic stability is described. The hydrogen bonds between the peripheral fragments of the donor and acceptor play the key role in the self-assembling. The influence of different structural factors on the thermodynamic stability of the supramolecular donor-acceptor complexes and the efficiency of charge-transfer interactions between the donor and acceptor are discussed. The driving forces of the reaction leading to exotic trimolecular charge-transfer complexes are considered.

Key words

crown ethers stilbenes azobenzenes viologen analogs self-assembling hydrogen bonding donor-acceptor complexes charge-transfer complexes 

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Copyright information

© Springer Science+Business Media, Inc.  2008

Authors and Affiliations

  • S. P. Gromov
    • 1
  • A. I. Vedernikov
    • 1
  • E. N. Ushakov
    • 1
  • M. V. Alfimov
    • 1
  1. 1.Photochemistry CenterRussian Academy of SciencesMoscowRussian Federation

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