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Russian Chemical Bulletin

, Volume 57, Issue 4, pp 754–760 | Cite as

Molten state and solvent-free systems studied by NMR spectroscopy: addition reactions catalyzed by transition metal complexes

  • V. P. AnanikovEmail author
  • I. P. Beletskaya
Reviews

Abstract

In the present review we address scarcely studied application area of NMR spectroscopy — investigation of molten state and solvent-free systems. In such a case NMR spectra are recorded without a solvent and without magnetic field stabilization on any nucleus. Taking our recent studies of catalytic addition of sulfur- and selenium-containing compounds to alkynes as examples, we describe most important practical aspects of NMR studies and their application for solving important chemical problems.

Key words

NMR spectroscopy solvent-free reactions molten state reactions transition metal catalysis alkynes 

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Copyright information

© Springer Science+Business Media, Inc.  2008

Authors and Affiliations

  1. 1.N. D. Zelinsky Institute of Organic ChemistryRussian Academy of SciencesMoscowRussian Federation
  2. 2.Department of ChemistryM. V. Lomonosov Moscow State UniversityMoscowRussian Federation

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