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Russian Chemical Bulletin

, Volume 57, Issue 2, pp 298–303 | Cite as

Modification of multiwalled carbon nanotubes by carboxy groups and determination of the degree of functionalization

  • M. N. Kirikova
  • A. S. Ivanov
  • S. V. SavilovEmail author
  • V. V. Lunin
Full Articles

Abstract

Multiwalled carbon nanotubes were modified by carboxy groups. Four independent methods for the determination of the degree of functionalization of the surface were proposed: 13C NMR spectroscopy, thermogravimetry, titrimetry, and fluorimetry. The first two methods show the total content of carboxy groups in the sample, and the latter two methods give information about the content of the surface groups only.

Key words

nanocarbon materials multiwalled carbon nanotubes carboxylation degree of functionalization 13C NMR spectroscopy TGA titrimetry fluorescence spectroscopy 

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Copyright information

© Springer Science+Business Media, Inc.  2008

Authors and Affiliations

  • M. N. Kirikova
    • 1
  • A. S. Ivanov
    • 1
  • S. V. Savilov
    • 1
    Email author
  • V. V. Lunin
    • 1
  1. 1.Department of ChemistryM. V. Lomonosov Moscow State UniversityMoscowRussian Federation

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