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Russian Chemical Bulletin

, Volume 56, Issue 8, pp 1537–1539 | Cite as

Synthesis of thiaazapodands from 4′-nitrobenzothiacrown ethers

  • S. N. Dmitrieva
  • N. I. Sidorenko
  • S. P. Gromov
Article

Abstract

A series of thiaazapodands were synthesized from 4′-nitrobenzothiacrown ethers by nucleophilic regioselective opening of the macrocycle on heating with methylamine in up to 94% yield.

Key words

crown compounds nitrobenzothiacrown ethers macrocyclic compounds methylamine podands aromatic nucleophilic substitution 

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Copyright information

© Springer Science+Business Media, Inc. 2007

Authors and Affiliations

  • S. N. Dmitrieva
    • 1
  • N. I. Sidorenko
    • 2
  • S. P. Gromov
    • 1
  1. 1.Photochemistry Center of the Russian Academy of SciencesMoscowRussian Federation
  2. 2.M. V. Lomonosov Moscow State Academy of Fine Chemical TechnologyMoscowRussian Federation

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