Russian Chemical Bulletin

, Volume 55, Issue 1, pp 84–88 | Cite as

Sandwich iridium complexes with the monoanionic carborane ligand [9-SMe2-7,8-C2B9H10]−

  • D. A. Loginov
  • M. M. Vinogradov
  • D. S. Perekalin
  • Z. A. Starikova
  • K. A. Lyssenko
  • P. V. Petrovskii
  • A. R. Kudinov
Article
Received:

Abstract

The reaction of the [(η-9-SMe2-7,8-C2B9H10)IrBr2]2 complex with Tl[Tl(η-7,8-C2B9H11)] afforded the iridacarborane compound (η-9-SMe2-7,8-C2B9H10)Ir(η-7,8-C2B9H11). The cationic complex [Cp*Ir(η-9-SMe2-7,8-C2B9H10)]+PF6− (5 · PF6, Cp* is pentamethylcyclopentadienyl) was synthesized by the reaction of [Cp*IrCl2]2 with Na[9-SMe2-7,8-C2B9H10]. The structures of (η-9-SMe2-7,8-C2B9H10)Ir(η-cod) (cod is 1,5-cyclooctadiene) and 5 · PF6 were established by X-ray diffraction.

Key words

iridium metallacarboranes sandwich compounds 
This is a preview of subscription content, log in to check access.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Y.-K. Yan, D. M. P. Mingos, T. E. Müller, D. J. Williams, and M. Kurmoo, J. Chem. Soc., Dalton Trans., 1994, 1735.Google Scholar
  2. 2.
    Y.-K. Yan, D. M. P. Mingos, T. E. Müller, D. J. Williams, and M. Kurmoo, J. Chem. Soc., Dalton Trans., 1995, 2509.Google Scholar
  3. 3.
    A. R. Kudinov, V. I. Meshcheryakov, P. V. Petrovskii, and M. I. Rybinskaya, Izv. Akad. Nauk, Ser. Khim., 1999, 177 [Russ. Chem. Bull., 1999, 48, 176 (Engl. Transl.)].Google Scholar
  4. 4.
    V. I. Meshcheryakov, P. S. Kitaev, K. A. Lyssenko, Z. A. Starikova, P. V. Petrovskii, Z. Janoušek, M. Corsini, F. Laschi, P. Zanello, and A. R. Kudinov, J. Organomet. Chem., 2005, 690, 4745.CrossRefGoogle Scholar
  5. 5.
    A. R. Kudinov, P. V. Petrovskii, V. I. Meshcheryakov, and M. I. Rybinskaya, Izv. Akad. Nauk, Ser. Khim., 1999, 1368 [Russ. Chem. Bull., 1999, 48, 1356 (Engl. Transl.)].Google Scholar
  6. 6.
    G. M. Rosair, A. J. Welch, and A. S. Weller, Organometallics, 1998, 17, 3227.CrossRefGoogle Scholar
  7. 7.
    A. R. Kudinov, D. S. Perekalin, P. V. Petrovskii, and G. V. Grintselev-Knyazev, Izv. Akad. Nauk, Ser. Khim., 2002, 1775 [Russ. Chem. Bull., Int. Ed., 2002, 51, 1928].Google Scholar
  8. 8.
    J. G. Planas, C. Vinas, F. Teixidor, M. B. Hursthouse, and M. E. Light, J. Chem. Soc., Dalton Trans., 2004, 2059.Google Scholar
  9. 9.
    A. R. Kudinov, V. I. Meshcheryakov, P. V. Petrovskii, and M. I. Rybinskaya, Izv. Akad. Nauk, Ser. Khim., 1999, 1817 [Russ. Chem. Bull., 1999, 48, 1794 (Engl. Transl.)].Google Scholar
  10. 10.
    A. R. Kudinov, D. S. Perekalin, P. V. Petrovskii, K. A. Lyssenko, G. V. Grintselev-Knyazev, and Z. A. Starikova, J. Organomet. Chem., 2002, 657, 115.CrossRefGoogle Scholar
  11. 11.
    A. R. Kudinov, D. S. Perekalin, and P. V. Petrovskii, Izv. Akad. Nauk, Ser. Khim., 2001, 1269 [Russ. Chem. Bull., Int. Ed., 2001, 50, 1334].Google Scholar
  12. 12.
    X. L. R. Fontaine, N. N. Greenwood, J. D. Kennedy, K. Nestor, M. Thornton-Pett, S. Hermanek, T. Jelinek, and B. Stibr, J. Chem. Soc., Dalton Trans., 1990, 681.Google Scholar
  13. 13.
    N. L. Douek and A. J. Welch, J. Chem. Soc., Dalton Trans., 1993, 1917.Google Scholar
  14. 14.
    P. L. Holland, R. A. Andersen, and R. G. Bergman, Organometallics, 1998, 17, 433.CrossRefGoogle Scholar
  15. 15.
    H. D. Smith, Jr. and M. F. Hawthorne, Inorg. Chem., 1974, 13, 2312.CrossRefGoogle Scholar
  16. 16.
    C. White, A. Yates, and P. M. Maitlis, Inorg. Synth., 1992, 29, 228.Google Scholar
  17. 17.
    SHELXTL v. 5.10, Structure Determination Software Suite, Bruker AXS, Madison, Wisconsin, USA, 1998.Google Scholar

Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • D. A. Loginov
    • 1
  • M. M. Vinogradov
    • 1
  • D. S. Perekalin
    • 1
  • Z. A. Starikova
    • 1
  • K. A. Lyssenko
    • 1
  • P. V. Petrovskii
    • 1
  • A. R. Kudinov
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

Personalised recommendations