Abstract
Systematic study of chlorination of fullerene C60 with inorganic chlorides SbCl5, VCl4, MoCl5, and KICl4 was carried out. Higher chlorofullerenes, viz., T h -C60Cl24, C60Cl28, C 2-C60Cl30, and D 3d -C60Cl30, can be prepared depending on the temperature and time of chlorination. The molecular and crystal structures of C60Cl24⋅VOCl3, C60Cl30⋅2CS2, and C60Cl30O1.22 were determined by single-crystal X-ray diffraction. Fullerenes C60Cl28 and C 2-C60Cl30 were shown to be only kinetically stable, whereas D 3d -C60Cl30 is a thermodynamically stable product. Transformations of less chlorinated fullerenes into more chlorinated products are accompanied by substantial changes in the addition patterns.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1608–1618, July, 2005.
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Troyanov, S.I., Shustova, N.B., Popov, A.A. et al. Synthesis and structures of C60 fullerene chlorides. Russ Chem Bull 54, 1656–1666 (2005). https://doi.org/10.1007/s11172-006-0018-4
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DOI: https://doi.org/10.1007/s11172-006-0018-4