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Synthesis and structures of C60 fullerene chlorides

Russian Chemical Bulletin Aims and scope

Abstract

Systematic study of chlorination of fullerene C60 with inorganic chlorides SbCl5, VCl4, MoCl5, and KICl4 was carried out. Higher chlorofullerenes, viz., T h -C60Cl24, C60Cl28, C 2-C60Cl30, and D 3d -C60Cl30, can be prepared depending on the temperature and time of chlorination. The molecular and crystal structures of C60Cl24⋅VOCl3, C60Cl30⋅2CS2, and C60Cl30O1.22 were determined by single-crystal X-ray diffraction. Fullerenes C60Cl28 and C 2-C60Cl30 were shown to be only kinetically stable, whereas D 3d -C60Cl30 is a thermodynamically stable product. Transformations of less chlorinated fullerenes into more chlorinated products are accompanied by substantial changes in the addition patterns.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1608–1618, July, 2005.

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Troyanov, S.I., Shustova, N.B., Popov, A.A. et al. Synthesis and structures of C60 fullerene chlorides. Russ Chem Bull 54, 1656–1666 (2005). https://doi.org/10.1007/s11172-006-0018-4

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  • DOI: https://doi.org/10.1007/s11172-006-0018-4

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