Russian Chemical Bulletin

, Volume 54, Issue 3, pp 615–622 | Cite as

Stabilization of tautomeric forms P(OH)3 and HP(OH)2 and their derivatives by coordination to palladium and nickel atoms in heterometallic clusters with the Mo3MQ44+ core (M = Ni, Pd; Q = S, Se)

  • M. N. Sokolov
  • E. V. Chubarova
  • K. A. Kovalenko
  • I. V. Mironov
  • A. V. Virovets
  • E. V. Peresypkina
  • V. P. Fedin
Article

Abstract

The cluster aqua complexes [Mo3(MCl)Q4(H2O)9]3+ (M = Pd or Ni) in hydrochloric acid solutions induce isomerization of the hydrophosphoryl compounds (HO)2P(O)H, (HO)P(O)H2, PhP(O)(OH)H, and Ph2P(O)H into the hydroxo tautomers P(OH)3, HP(OH)2, PhP(OH)2, and Ph2P(OH), which are stabilized by coordination of the phosphorus atom to the Pd or Ni atoms. The reactions were studied by 31P NMR and UV-Vis spectroscopy. The kinetics of the reactions of phosphorous acid with [Mo3(PdCl)Q4(H2O)9]3+ was investigated by spectrophotometry. The [Mo3(Pd(PhP(OH)2))S4(H2O)2Cl7]3− complex was isolated as a supramolecular adduct with cucurbit [8]uril, and the [Mo3(Ni(P(OH)3))S4(H2O)8Cl]3+ complex was isolated as an adduct with cucurbit [6]uril. The structures of both compounds were established by X-ray diffraction analysis.

Key words

molybdenum palladium chalcogenide clusters cucurbituril phosphorus acids 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    M. N. Sokolov, A. V. Virovets, D. N. Dybtsev, E. V. Chubarova, V. P. Fedin, and D. Fenske, Inorg. Chem., 2001, 40, 4816.CrossRefPubMedGoogle Scholar
  2. 2.
    M. N. Sokolov, R. Hernandez-Molina, W. Clegg, V. P. Fedin, and A. Mederos, Chem. Commun., 2003, 140.Google Scholar
  3. 3.
    M. N. Sokolov, E. V. Chubarova, A. V. Virovets, R. Llusar, and V. P. Fedin, J. Cluster Science, 2003, 14, 227.CrossRefGoogle Scholar
  4. 4.
    R. Hernandez-Molina, M. N. Sokolov, I. V. Kalinina, M. Clausen, E. Chubarova, R. Llusar, and C. Vicent, Proc. 36th Intern. Conf. on Coordination Chemistry, Merida, 2004, Π-287.Google Scholar
  5. 5.
    C. S. Bahn, A. Tan, and S. Harris, Inorg. Chem., 1998, 37, 2770.CrossRefPubMedGoogle Scholar
  6. 6.(a)
    Phosphorus. An Outline of Its Chemistry, Biochemistry and Technology, Ed. D. Corbridge, Elsevier, Amsterdam, 1980, 51 pp.; (b) Phosphorus and Its Compounds, Ed. J. R. Van Wazer, Interscience Publishers, Inc., New York, 1958, 170 pp..Google Scholar
  7. 7.
    S. G. Kozlova, S. P. Gabuda, and R. Blinc, Chem. Phys. Lett., 2003, 376, 364.CrossRefGoogle Scholar
  8. 8.
    W. Henderson, M. T. Leach, B. K. Nickolson, and M. Sabat, J. Chem. Soc., Dalton Trans., 1995, 2109.Google Scholar
  9. 9.
    J. E. Griffiths and A. B. Burg, J. Am. Chem. Soc., 1962, 84, 3442.CrossRefGoogle Scholar
  10. 10.
    D. M. Saysell, G. J. Lamprecht, J. Darkwa, and A. G. Sykes, Inorg. Chem., 1996, 35, 5531.CrossRefPubMedGoogle Scholar
  11. 11.
    R. L. Sernaglia and D. W. Franco, Inorg. Chem., 1989, 28, 3485.CrossRefGoogle Scholar
  12. 12.
    C. Hollatz, A. Schier, and H. Schmidbaur, Inorg. Chim. Acta, 2000, 300–302, 191.CrossRefGoogle Scholar
  13. 13.
    C. S. Kraihanzel, J. Organomet. Chem., 1974, 73, 137.CrossRefGoogle Scholar
  14. 14.
    H. Vahrenkamp, Chem. Ber., 1972, 105, 3574.Google Scholar
  15. 15.
    C. C. Kraihanzel and C. M. Bartish, J. Am. Chem. Soc., 1972, 94, 1972.CrossRefGoogle Scholar
  16. 16.
    H. Noth, H. Reith, and V. Thorn, Z. Anorg. Allg. Chem., 1979, 458, 219.CrossRefGoogle Scholar
  17. 17.
    S. Patel, S. J. A. Pope, and G. Reid, Polyhedron, 1998, 17, 2345.CrossRefGoogle Scholar
  18. 18.
    F. Bosolo and R. G. Pearson, Mechanisms of Inorganic Reactions. A Study of Metal Complexes in Solution, J. Wiley and Sons, Inc., New York—London—Sydney, 1967.Google Scholar
  19. 19.
    N. R. Draper and H. Smith, Applied Regression Analysis, J. Wiley and Sons, New York— Chichester—Brisbane—Toronto—Singapore, 1981.Google Scholar
  20. 20.
    D. M. Saysell, C. D. Borman, C. H. Kwak, and A. G. Sykes, Inorg. Chem., 1996, 35, 173.CrossRefPubMedGoogle Scholar
  21. 21.
    K. Herbst, P. Zanello, M. Corsini, N. D’Amello, L. Dahlenburg, and M. Brorson, Inorg. Chem., 2003, 42, 974.CrossRefPubMedGoogle Scholar
  22. 22.
    M. N. Sokolov, E. V. Chubarova, R. Hernandez-Molina, M. Clausen, D. Yu. Naumov, C. Vicent, R. Llusar, and V. P. Fedin, Eur. J. Inorg. Chem., 2005, 2139.Google Scholar
  23. 23.
    M. N. Sokolov, R. Hernandez-Molina, D. N. Dybtsev, E. V. Chubarova, S. F. Solodovnikov, N. V. Pervukhina, C. Vicent, R. Llusar, and V. P. Fedin, Z. Anorg. Allg. Chem., 2002, 628, 2335.CrossRefGoogle Scholar
  24. 24.
    T. Shibahara, M. Yamasaki, H. Akashi, and T. Katayama, Inorg. Chem., 1991, 30, 2693.CrossRefGoogle Scholar
  25. 25.
    V. P. Fedin, V. Gramlich, M. Worle, and T. Weber, Inorg. Chem., 2001, 40, 1074.CrossRefGoogle Scholar
  26. 26.
    T. Shibahara, S. Mochida, and G. Sakane, Chem. Lett., 1993, 89.Google Scholar
  27. 27.
    D. A. Allison, J. Clardy, and J. G. Verkade, Inorg. Chem., 1972, 11, 2804.CrossRefGoogle Scholar
  28. 28.
    A. Tellenbach and M. Jansen, Eur. J. Inorg. Chem., 2003, 3759.Google Scholar
  29. 29.
    T. Murata, Y. Mizobe, H. Gao, Y. Ishii, T. Wakabayashi, F. Nakano, T. Tanase, S. Yano, M. Hidai, I. Echizen, H. Nanikawa, and S. Motomura, J. Am. Chem. Soc., 1994, 116, 3389.CrossRefGoogle Scholar
  30. 30.
    V. P. Fedin and A. G. Sykes, Inorg. Synth., 2002, 33, 162.Google Scholar
  31. 31.
    V. P. Fedin, M. S. Seo, D. M. Saysell, D. N. Dybtsev, M. R. J. Elsegood, W. Clegg, and A. G. Sykes, J. Chem. Soc., Dalton Trans., 2002, 138.Google Scholar
  32. 32.
    A. Day, A. P. Arnold, R. D. Blauch, and B. Snushall, J. Org. Chem., 2001, 66, 8094.CrossRefPubMedGoogle Scholar
  33. 33.
    W. A. Freeman, W. L. Mock, and N. Y. Shih, J. Am. Chem. Soc., 1981, 103, 7367.CrossRefGoogle Scholar
  34. 34.
    APEX2 (Version 1.08), SAINT (Version 7.03), and SADABS (Version 2.11), Bruker Advanced X-ray Solutions, Bruker AXS, Inc., Madison (Wisconsin, USA), 2004.Google Scholar
  35. 35.
    G. M. Sheldrick, SHELXS97 and SHELXL97, Programs for the Refinement of Crystal Structures, Gottingen University, Gottingen (Germany), 1997.Google Scholar

Copyright information

© Springer Science+Business Media, Inc. 2005

Authors and Affiliations

  • M. N. Sokolov
    • 1
  • E. V. Chubarova
    • 1
  • K. A. Kovalenko
    • 1
  • I. V. Mironov
    • 1
  • A. V. Virovets
    • 1
  • E. V. Peresypkina
    • 1
  • V. P. Fedin
    • 1
  1. 1.A. V. Nikolaev Institute of Inorganic ChemistrySiberian Branch of the Russian Academy of SciencesNovosibirskRussian Federation

Personalised recommendations