Russian Chemical Bulletin

, Volume 53, Issue 10, pp 2224–2228 | Cite as

Synthesis and mass spectrometric study of α,ω-diallylpermethyloligosilanes

  • D. Yu. Larkin
  • A. P. Pleshkova
  • E. G. Kononova
  • N. A. Chernyavskaya
  • A. I. Chernyavskii
Article

Abstract

Representatives of the homologous series of α,ω-diallylpermethyloligosilanes were synthesized for the first time by the reaction of α,ω-dichloropermethyloligosilanes Cl(Me2Si)nCl (n = 2–6) with allylmagnesium chloride. Fragmentation of α,ω-diallylpermethyloligosilanes under electron impact ionization was studied by mass spectrometry.

Key words

α,ω-dichloropermethyloligosilanes allylmagnesium chloride α,ω-diallylpermethyloligosilanes NMR spectra IR spectra UV spectra mass spectra 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    A. M. Tsirlin and N. A. Popova, Keramikoobrazuyushchie kremniiorganicheskie polimery — polikarbosilany [Ceramic-Forming Organosilicon Polymers — Polycarbosilanes], Izd-vo NIITEKhIM, Moscow, 1990, 58 pp. (in Russian).Google Scholar
  2. 2.
    H. Sakurai, A. Hosomi, and M. Kumada, Tetrahedron Lett., 1968, 2469.Google Scholar
  3. 3.
    V. F. Mironov, V. D. Sheludyakov, and V. I. Zhun’, Zh. Obshch. Khim., 1977, 47, 1756 [J. Gen. Chem. USSR, 1977, 47 (Engl. Transl.)].Google Scholar
  4. 4.
    A. Yu. Osadchev, A. R. Pushkarev, Yu. Yu. Nikitina, V. V. Shamanin, and S. S. Skorokhodov, Zh. Obshch. Khim., 2000, 70, 1470 [Russ. J. Gen. Chem., 2000, 70 (Engl. Transl.)].Google Scholar
  5. 5.
    Yu. P. Egorov, L. A. Leites, and V. F. Mironov, Zh. Strukt. Khim., 1961, 2, 563 [J. Struct. Chem. (USSR), 1961 (Engl. Transl.)].Google Scholar
  6. 6.
    L. A. Leites, S. S. Bukalov, T. S. Yadritseva, B. A. Antipova, and V. V. Dement’ev, Macromolecules, 1992, 25, 2991.CrossRefGoogle Scholar
  7. 7.
    M. R. Litzow and T. R. Spalding, Mass Spectrometry of Inorganic and Organometallic Compounds, Ed. M. F. Lappert, SPC, Amsterdam, 1973, 573 pp.Google Scholar
  8. 8.
    C. H. Middlecamp, W. Wojnowski, and R. West, J. Organomet. Chem., 1977, 140, 133.CrossRefGoogle Scholar
  9. 9.
    H. G. Schuster and E. Hengge, Monatsh. Chem., 1983, 114, 1305.Google Scholar
  10. 10.
    Y. Nakadaira, Y. Kobayashi, and H. Sakurai, J. Organomet. Chem., 1973, 63, 79.Google Scholar
  11. 11.
    E. Hengge and G. Miklau, Z. Anorg. Allg. Chem., 1984, 508, 43.CrossRefGoogle Scholar
  12. 12.
    NIST/EPA/NIH Mass Spectral Library, V. 1.0, National Institute of Standards and Technology, Gaithersburg (Mary land, USA), 2002.Google Scholar
  13. 13.
    A. I. Chernyavskii and N. A. Chernyavskaya, Izv. Akad. Nauk, Ser. Khim., 2002, 1607 [Russ. Chem. Bull., Int. Ed., 2002, 51, 1751].Google Scholar

Copyright information

© Springer Science+Business Media, Inc. 2004

Authors and Affiliations

  • D. Yu. Larkin
    • 1
  • A. P. Pleshkova
    • 1
  • E. G. Kononova
    • 1
  • N. A. Chernyavskaya
    • 1
  • A. I. Chernyavskii
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

Personalised recommendations