Russian Chemical Bulletin

, Volume 53, Issue 10, pp 2175–2178 | Cite as

Heterometallic hafnocene(+4) aluminum hydride complex [(ηp5-C5H5)2Hf(H)(μ2-H)Al(H)Br(μ2-OC4H9)]2

  • A. I. Sizov
  • T. M. Zvukova
  • A. A. Gorkovskii
  • Z. A. Starikova
  • B. M. Bulychev
Article
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Revised:

Abstract

The [Cp2HfH2Al(H)Br(OBu)]2 complex (1) was prepared by the reaction of Cp2HfBr2 with AlH3 in THF and characterized by X-ray crystallography. The formation of dinuclear complex 1 proceeds through the intermediate formation (as a result of cleavage of THF molecules) of the >Al(μ-OBu)2Al< fragment. The latter is linked to two hafnocene dihydride molecules by the Hf-H-Al hydrogen bridges. The Hf atom in complex 1 has a 16-electron environment.

Key words

hafnocene aluminum hydride crystal structure 
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Copyright information

© Springer Science+Business Media, Inc. 2004

Authors and Affiliations

  • A. I. Sizov
    • 1
  • T. M. Zvukova
    • 1
  • A. A. Gorkovskii
    • 1
  • Z. A. Starikova
    • 2
  • B. M. Bulychev
    • 1
  1. 1.Department of ChemistryMoscow State University, Leninskie GoryMoscowRussian Federation
  2. 2.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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