Russian Journal of Applied Chemistry

, Volume 78, Issue 2, pp 295–300 | Cite as

Concentration Effect in Copolymerization of Sodium 2-Acrylamido-2-methylpropanesulfonate with N-Vinylpyrrolidone in Aqueous Solutions

  • V. F. Kurenkov
  • T. A. Zhelonkina
  • V. I. Kovalenko
Macromolecular Chemistry and Polymeric Materials
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Abstract

The kinetics of copolymerization of sodium 2-acrylamido-2-methylpropanesulfonate with N-vinyl-pyrrolidone in aqueous solutions in the presence of potassium persulfate at 40 – 70°C and the molecular characteristics of the resulting complexes were studied, as influenced by the total concentration of the initial monomer mixture, comonomer ratio, temperature, and conversion. The kinetic data were explained taking into account the state of the ionic groups, electrostatic interactions between the reacting particles, and complexation of comonomers in the course of copolymerization.

Keywords

Sodium Potassium Aqueous Solution Electrostatic Interaction Total Concentration 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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REFERENCES

  1. 1.
    Kurenkov, V.F., Sharapova, Z.F., and Khairullin, M.R., Zh. Prikl. Khim., 1999, vol. 72, no.8, pp. 1374–1378.Google Scholar
  2. 2.
    Shevtsova, S.A., Barkhanova, T.A., Zhelonkina, T.A., and Kurenkov, V.F., in Materialy konferentsii “III Kirpichnikovskie chteniya” (Proc. Conf. “III Kirpichnikov Readings”), Kazan: Kazan. Gos. Tekhnol. Univ., 2003, pp. 308–311.Google Scholar
  3. 3.
    Kabanov, V.A. and Topchiev, D.A., Polimerizatsiya ionizuyushchikhsya monomerov (Polymerization of Ionizable Monomers), Moscow: Nauka, 1975.Google Scholar
  4. 4.
    Kurenkov, V.F. and Myagchenkov, V.A., Eur. Polym. J., 1979, vol. 15, pp. 849–862.Google Scholar
  5. 5.
    Kurenkov, V.F. and Myagchenkov, V.A., Zh. Prikl. Khim., 1999, vol. 72, no.6, pp. 881–890.Google Scholar
  6. 6.
    Kurenkov, V.F., Sirotkin, R.O., Beryachkova, E.A., and Khairullin, M.R., Zh. Prikl. Khim., 1999, vol. 72, no.8, pp. 1533–1537.Google Scholar
  7. 7.
    Charlot, G., Les methods de la chimie analytique. Analyse quantitative minerale, Paris: Masson, 1961, 4th ed.Google Scholar
  8. 8.
    Kholodnova, L.V., Pavlyuchenko, V.N., Alekseeva, Z.M., and Andreeva, A.I., in Kataliticheskie i initsiiruyushchie sistemy dlya sinteza i modifikatsii polimerov (Catalytic and Initiating Systems for Synthesis and Modification of Polymers), Leningrad: Plastpolimer, 1984, pp. 90–104.Google Scholar
  9. 9.
    Kolthoff, I.M. and Miller, I.K., J. Am. Chem. Soc., 1951, vol. 73, no.7, pp. 3055–3059.Google Scholar
  10. 10.
    2-Acrylamido-2-methylpropane Sulfonic Acid Monomer, Wickliffe, Ohio (USA): Lubrizol, 1994, pp. 1–18.Google Scholar
  11. 11.
    Sidel’kovskaya, F.P., Khimiya N-vinilpirrolidona i ego polymerov (Chemistry of N-Vinylpyrrolidone and Its Polymers), Moscow: Nauka, 1970.Google Scholar
  12. 12.
    Schultz, D.N., Kitano, K., Danik, J.F., and Kaladas, J.J., Polym. Mater. Sci. Eng., 1987, vol. 57, pp. 149–153.Google Scholar
  13. 13.
    Topchiev, D.A., Shakirov, R.Z., Kalinina, L.P., et al., Vysokomol. Soedin., Ser. A, 1972, vol. 14, no.3, pp. 581–586.Google Scholar
  14. 14.
    Gromov, V.F., Bogachev, Yu.S., Bune, E.V., et al., Vysokomol. Soedin., 1993, vol. 35, no.1, pp. 7–12.Google Scholar
  15. 15.
    Kabanov, V.A., Zubov, V.P., and Semchikov, Yu.D., Kompleksno-radikal’naya polimerizatsiya (Coordination Radical Polymerization), Moscow: Khimiya, 1987.Google Scholar

Copyright information

© MAIK “Nauka/Interperiodica” 2005

Authors and Affiliations

  • V. F. Kurenkov
    • 1
  • T. A. Zhelonkina
    • 1
  • V. I. Kovalenko
    • 1
  1. 1.Kazan State Technological UniversityKazan, TatarstanRussia

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