Russian Journal of Applied Chemistry

, Volume 78, Issue 2, pp 188–192 | Cite as

Complex Energetic Perchlorates of Cobalt(III) Amminates, with Cyclopentamethylenetetrazole as Ligand

  • A. Yu. Zhilin
  • M. A. Ilyushin
  • I. V. Tselinskii
  • Yu. A. Nikitina
  • A. S. Kozlov
  • I. V. Shugalei
Inorganic Synthesis and Industrial Inorganic Chemistry


Energetic metal complexes, pentammine(cyclopentamethylenetetrazole)cobalt(III) perchlorate and tetraammine-bis(cyclopentamethylenetetrazole)cobalt(III) perchlorate, were obtained by reaction of aquapentaamminecobalt(III) and diaquatetraamminecobalt(III) ions with cyclopentamethylenetetrazole. Microwave heating was used, together with the conventional convective heating, for thermal activation of the process. The thermal decomposition of the compounds synthesized was studied. The explosive characteristics and toxicity of the metal complexes were determined.


Toxicity Microwave Cobalt Explosive Thermal Decomposition 
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Copyright information

© MAIK “Nauka/Interperiodica” 2005

Authors and Affiliations

  • A. Yu. Zhilin
    • 1
  • M. A. Ilyushin
    • 1
  • I. V. Tselinskii
    • 1
  • Yu. A. Nikitina
    • 1
  • A. S. Kozlov
    • 1
  • I. V. Shugalei
    • 1
  1. 1.St. Petersburg State Technological Institute (Technical University)St. PetersburgRussia

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